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Acetonitrile-trichloridobis(cyclo-hexyl-diphenyl-phosphane)rhodium(III) acetonitrile disolvate.

ABSTRACT: In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol-ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol-ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol-ecule in a distorted octa-hedral geometry. Intra-molecular C-H?Cl inter-actions are observed. The uncoordinated acetonitrile mol-ecule is disordered over two sites with occupancies of 0.588?(4) and 0.412?(4).

SUBMITTER: Muller TJ

PROVIDER: S-EPMC3238697 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Acetonitrile-trichloridobis(cyclo-hexyl-diphenyl-phosphane)rhodium(III) acetonitrile disolvate.

Muller Theunis J TJ Visser Hendrik G HG Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol-ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol-ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol-ecule in a distorted octa-hedral geometry. Intra-molecular C-H⋯Cl inter-actions are observed. The uncoordinated acetonitrile mol-ecule is disordered over tw ...[more]

PMID: 22199574

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