Unknown

Dataset Information

0

Chlorido[1-(pyridin-2-yl)ethanone oximato-?N,N'][1-(2-pyrid-yl)ethanone oxime-?N,N']copper(II) trihydrate.


ABSTRACT: In the title compound, [Cu(C(7)H(7)N(2)O)Cl(C(7)H(8)N(2)O)]·3H(2)O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.192. The two organic ligands are linked by an intra-molecular O-H?O hydrogen bond. In the crystal, mol-ecules are linked by O-H?O and O-H?Cl hydrogen bonds. The title compound is the hydrated form of a previously reported structure [Wu & Wu (2008 ?). Acta Cryst. E64, m828]. There are only slight variations in the mol-ecular geometries of the two compounds.

SUBMITTER: Qiu X 

PROVIDER: S-EPMC3238715 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

altmetric image

Publications

Chlorido[1-(pyridin-2-yl)ethanone oximato-κN,N'][1-(2-pyrid-yl)ethanone oxime-κN,N']copper(II) trihydrate.

Qiu Xiumin X   Li Leilei L   Li Dacheng D  

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12


In the title compound, [Cu(C(7)H(7)N(2)O)Cl(C(7)H(8)N(2)O)]·3H(2)O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.192. The two organic ligands are linked by an intra-molecular O-H⋯O hydrogen bond. In the crystal, mol-ecules are linked by O-H⋯O and O-H⋯Cl hydrogen bonds. The title compound is the hydrated form of  ...[more]

Similar Datasets

| S-EPMC3393154 | biostudies-other
| S-EPMC2961395 | biostudies-literature
| S-EPMC3254275 | biostudies-literature
| S-EPMC3393160 | biostudies-other
| S-EPMC3089113 | biostudies-literature
| S-EPMC3379113 | biostudies-literature
| S-EPMC3201516 | biostudies-literature
| S-EPMC3344299 | biostudies-literature
| S-EPMC3588330 | biostudies-literature
| S-EPMC3238744 | biostudies-literature