Browse
Submit Data
Databases
API
Help

Dataset Information

12 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Chlorido(dimethyl sulfoxide-?S)[2-(2-pyrid-yl)phenyl-?N,C]platinum(II).

ABSTRACT: In the title compound, [Pt(C(11)H(8)N)Cl(C(2)H(6)OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt-S = 2.2181?(11)?Å] and the chlorido ligand is trans to the carbon donor of 2-(2-pyrid-yl)phenyl [Pt-Cl = 2.4202?(10)?Å]. The [2-(2-pyrid-yl)phen-yl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent inter-planar separations of 3.44?(9) and 3.50?(2)?Å.

SUBMITTER: Kobayashi M

PROVIDER: S-EPMC2959355 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Chlorido(dimethyl sulfoxide-κS)[2-(2-pyrid-yl)phenyl-κN,C]platinum(II).

Kobayashi Masayuki M Masaoka Shigeyuki S Sakai Ken K

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

In the title compound, [Pt(C(11)H(8)N)Cl(C(2)H(6)OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt-S = 2.2181 (11) Å] and the chlorido ligand is trans to the carbon donor of 2-(2-pyrid-yl)phenyl [Pt-Cl = 2.4202 (10) Å]. The [2-(2-pyrid-yl)phen-yl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent inter-planar separations of 3.44 (9) and 3.50 (2) Å. ...[more]

PMID: 21201060

Similar Datasets

trans-Chlorido(dimethyl sulfoxide-?S)(pyridine-2-carboxyl-ato-?N,O)platinum(II).

Project description:In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxyl-ate (pic) anionic ligand, one S atom of the dimethyl sulfoxide mol-ecule and one Cl ion. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through all the atoms of the complex except the methyl atoms of the dimethyl sulfoxide. The mol-ecules are stacked in columns along the b axis with a Pt?Pt distance of 4.9508?(5)?Å. Within the column, inter-molecular C-H?O hydrogen bonds and weak ?-? inter-actions between adjacent pyridine rings are present, the shortest centroid-centroid distance being 5.153?(4)?Å.

| S-EPMC2983664 | biostudies-literature

Chlorido[1,1'-(5-methyl-1,3-phenyl-ene)bis-(3,5-dimethyl-1H-imidazol-2-yl-idene)]platinum(II).

Project description:In the title compound, [Pt(C17H19N4)Cl], the Pt(II) cation is C,C',C''-chelated by the 1,1'-(5-methyl-1,3-phenyl-ene)bis-(3,5-dimethyl-1H-imidazolyl-idene) anion and coordinated by a Cl(-) anion in a distorted square-planar coordination geometry. ?-? stacking is observed between nearly parallel imidazole and benzene rings of adjacent mol-ecules, the centroid-centroid distance being 3.802?(4)?Å.

| S-EPMC3629494 | biostudies-literature

Chlorido(dimethyl sulfoxide)(pyridine-2-thiol-ato N-oxide-?S,O)platinum(II).

Project description:The asymmetric unit of the title compound, [Pt(C(5)H(4)NOS)Cl(C(2)H(6)OS)], contains two independent complex mol-ecules having similar geometries. Each Pt(II) atom is four-coordinated in a distorted square-planar geometry by S and O atoms of one pyridine N-oxide ligand, the S atom of one dimethyl sulfoxide mol-ecule and one terminal Cl(-) ion. The mol-ecules are linked into a three-dimensional framework by C-H?O and C-H?Cl hydrogen bonds.

| S-EPMC2961893 | biostudies-other

Di-?-chlorido-bis[chloridobis(dimethyl sulfoxide-?O)tin(II)].

Project description:The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn?Cl [3.691?(2)?Å] inter-actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta-coordinated and have a distorted octa-hedral ?-SnCl(3)O(2) coordination geometry. The O atoms from the dimethyl sulfoxide mol-ecules occupy trans positions, while the Cl atoms exhibit a meridional arrangement.

| S-EPMC3100018 | biostudies-literature

Chlorido[6-phenyl-4-(p-tol-yl)-2,2'-bipyridyl-κN,N']platinum(II).

Project description:The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent mol-ecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short inter-molecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC(3) and PtN(2)C(2) rings, respectively, indicate the existence of π-π inter-actions, which link the mol-ecules into stacks along the a axis. The crystal structure is further stabilized by weak C-H⋯π inter-actions.

| S-EPMC2961937 | biostudies-literature

Bis(?-4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolato)bis-[chlorido(dimethyl sulfoxide)-iron(III)] dimethyl sulfoxide disolvate.

Project description:In the centrosymmetric dimeric title complex, [Fe(2)(C(14)H(10)N(2)O(4))(2)Cl(2)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, two {Fe(L)Cl(DMSO)} units (L is the tridentate ligand 4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolate; DMSO is dimethyl sulfoxide) are bridged by two O atoms, with an Fe?Fe separation of 3.1838?(8)?Å. The coordination polyhedron of the Fe(III) atoms can be described as distorted octa-hedral, with four Fe-O, one Fe-N and one Fe-Cl coordination bonds. The L ligand is not planar, the dihedral angle between the 2-(oxidometh-yl)phen-yl]imino and 4-nitro-2-(imino-meth-yl)phenolate planes being 48.54?(9)°. The solvent DMSO molecule is disordered over two orientations with equal occupancy.

| S-EPMC3344389 | biostudies-literature

Bis(chlorido)(dimethyl-sulfoxide-?O)barium(II).

Project description:The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl-sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa-hedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are inter-connected by the DMSO mol-ecules, forming a three-dimensional network.

| S-EPMC3515089 | biostudies-other

Chlorido{5-chloro-2-[2-(methyl-sulfanyl)phenyl-diazen-yl]phenyl}-platinum(II).

Project description:The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra-coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol-ecules dimerize through a nonbonded S?S inter-action [S?S = 3.523?(18)?Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter-molecular ?-? inter-actions; the centroid-centroid distances are 3.804?(3), 3.638?(3), 3.804?(3) and 3.638?(3)?Å, and the corresponding perpendicular distances are 3.369, 3.448, 3.406 and 3.466?Å.

| S-EPMC2960293 | biostudies-other

Triaqua-chlorido[3-dimethyl-amino-1-(2-pyrid-yl)prop-2-en-1-one-?N]manganese(II) chloride.

Project description:In the title compound, [MnCl(C(10)H(12)N(2)O)(H(2)O)(3)]Cl, the Mn(II) ion has a distorted octa-hedral coordination environment formed by one N and one O atom from the chelating 3-dimethyl-amino-1-(2-pyrid-yl)prop-2-en-1-one ligand, one chloride anion and three coordinated water mol-ecules. Inter-molecular O-H?O and O-H?Cl hydrogen bonds link the cations and anions into layers parallel to the ac plane.

| S-EPMC2977233 | biostudies-literature

(2-{[4-(Chlorido-mercur-yl)phen-yl]imino-meth-yl}pyridine-κ(2) N,N')di-iodido-mercury(II) dimethyl sulfoxide monosolvate.

Project description:The title dimethyl sulfoxide solvate, [Hg2(C12H9ClN2)I2]·C2H6OS, features tetra-hedrally and linearly coordinated Hg(II) atoms. The distorted tetrahedral coordination sphere is defined by chelating N atoms that define an acute angle [69.6 (3)°] and two I atoms that form a wide angle [142.80 (4)°]. The linearly coordinated Hg(II) atom [177.0 (4)°] exists with a donor set defined by C and Cl atoms. Secondary inter-actions are apparent in the crystal packing with the tetra-hedrally and linearly coordinated Hg(II) atoms expanding their coordination environments by forming weak Hg⋯I [3.772 (7) Å] and Hg⋯O [2.921 (12) Å] inter-actions, respectively. Mercury-containing mol-ecules stack along the a axis, are connected by π-π inter-actions [inter-centroid distance between pyridine and benzene rings = 3.772 (7) Å] and define channels in which the dimethyl sulfoxide mol-ecules reside. The latter are connected by the aforementioned Hg⋯O inter-actions as well as C-H⋯I and C-H⋯O inter-actions, resulting in a three-dimensional architecture.

| S-EPMC3884979 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data