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Bis{3-[2-(methyl-sulfon-yl)pyrimidin-4-yl]pyridinium} tetra-chloridocadmium.

ABSTRACT: In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787?(10) and 2.4410?(10)?Å. A chain along the c axis is formed by C-H?N hydrogen-bonding inter-actions and a weak ?-? inter-action is observed between the pyrimidine rings of two adjacent parallel chains [centroid-centroid distance = 3.722?(2)?Å]. N-H?Cl, CN-H?Cl and N-H?O interactions also occur.

SUBMITTER: Hu D 

PROVIDER: S-EPMC3238717 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Bis{3-[2-(methyl-sulfon-yl)pyrimidin-4-yl]pyridinium} tetra-chloridocadmium.

Hu Dahua D   Liu Xia X  

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the c axis is formed by C-H⋯N hydrogen-bonding inter-actions and a weak π-π inter-action is observed between the pyrimidine rings of two adjacent parallel chains [centroid-centroid distance = 3.722 (2) Å]. N-H⋯Cl, CN-H⋯Cl and N-H⋯O interactions also occur. ...[more]

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