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Tetra-n-butyl-ammonium tricyanido[N-(2-pyridyl-carbon-yl)pyridine-2-carbox-imidato]ferrate(III) dihydrate.

ABSTRACT: In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl-ammonium ion has a tetra-hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl-carbon-yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa-hedral geometry. O-H?O and O-H?N hydrogen bonds link the components in the crystal structure.

SUBMITTER: Xiao Y

PROVIDER: S-EPMC3238764 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Tetra-n-butyl-ammonium tricyanido[N-(2-pyridyl-carbon-yl)pyridine-2-carbox-imidato]ferrate(III) dihydrate.

Xiao Yunyun Y Shen Xiaoping X Li Yizhi Y

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl-ammonium ion has a tetra-hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl-carbon-yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa-hedral geometry. O-H⋯O and O-H⋯N hydrogen bonds link the components in the crystal structure. ...[more]

PMID: 22199641

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