Unknown

Dataset Information

0

Dibenzo[a,e]penta-cyclo-[12.2.1.1.0.0]octa-deca-2(13),5(10)-diene.

ABSTRACT: In the title compound, C(26)H(24), the central cyclo-octa-tetra-ene ring has a boat conformation, and the mol-ecule is saddle shaped. The seat is defined by the mean plane of the four-atom attachment points (r.m.s. deviation = 0.014 Å) of the two bicyclo-heptane substituents. These substituents comprise the pommel and cantle, with each mean plane defined by four atoms proximate to the seat (r.m.s. deviations = 0.001 and 0.000 Å). Relative to the seat, the pommel and cantle bend up 33.36 (5) and 34.22 (4)°, while the benzo units (flaps, r.m.s. deviations = 0.008 and 0.013 Å) bend down 33.48 (4) and 36.58 (4)°.

SUBMITTER: Gautreaux D 

PROVIDER: S-EPMC3238874 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Dibenzo[a,e]penta-cyclo-[12.2.1.1.0.0]octa-deca-2(13),5(10)-diene.

Gautreaux Dixie D   Nauman Tamara R Schaller TR   Fronczek Frank R FR   Watkins Steven F SF  

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the title compound, C(26)H(24), the central cyclo-octa-tetra-ene ring has a boat conformation, and the mol-ecule is saddle shaped. The seat is defined by the mean plane of the four-atom attachment points (r.m.s. deviation = 0.014 Å) of the two bicyclo-heptane substituents. These substituents comprise the pommel and cantle, with each mean plane defined by four atoms proximate to the seat (r.m.s. deviations = 0.001 and 0.000 Å). Relative to the seat, the pommel and cantle bend up 33.36 (5) and  ...[more]

Similar Datasets

Unknown (1R,2R,5R,6R,9S,10S,13S,14S)-1,6,7,8,9,14,15,16,17,17-Decachloro-penta-cyclo-[12.2.1.1.0.0]octa-deca-7,15-diene.
| S-EPMC2961698 | biostudies-literature
Unknown (1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca-chloro-penta-cyclo-[12.2.1.1.0.0]octa-deca-7,15-diene.
| S-EPMC2961815 | biostudies-literature
Unknown syn-Dispiro-[1,3-dioxolane-2,17'-penta-cyclo-[12.2.1.1.0.0]octa-decane-18',2''-[1,3]dioxolane]-7',15'-diene.
| S-EPMC3009060 | biostudies-literature
Unknown Penta-cyclo-[9.3.1.1(2,6).1(4,8).1(9,13)]octa-deca-1(2),8(9)-diene.
| S-EPMC3393958 | biostudies-literature
Unknown anti-1',6',7',8',9',14',15',16'-Octa-chloro-dispiro-[1,3-dioxolane-2,17'-penta-cyclo-[12.2.1.1.0.0]octa-decane-18',2''-1,3-dioxolane]-7',15'-diene.
| S-EPMC3007477 | biostudies-literature
Unknown 13-Hydr-oxy-4,16-dimethyl-4,16-diaza-penta-cyclo-[12.3.1.0.0.0]octa-deca-7(12),8,10-triene-6,18-dione.
| S-EPMC2977829 | biostudies-literature
Unknown Penta-cyclo-[8.2.1.1(4,7).0(2,9).0(3,8)]tetra-deca-5,11-diene.
| S-EPMC3470317 | biostudies-literature
Unknown Dispiro-[cyclo-propane-1,5'-endo-tricyclo-[5.2.1.0]deca-3,8-diene-10',1''-cyclo-propane].
| S-EPMC3006803 | biostudies-other
Unknown (η-Cyclo-octa-1,5-diene)diiodidoplatinum(II).
| S-EPMC2970000 | biostudies-literature
Unknown Chlorido(?-1,5-cyclo-octa-diene)[(penta-fluoro-eth-yl)diphenyl-phosphane]iridium(I).
| S-EPMC3050217 | biostudies-other