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(?-Cyclo-octa-1,5-diene)diiodidoplatinum(II).

ABSTRACT: The monoclinic title complex, [PtI(2)(C(8)H(12))], characterized by a twisted cyclo-octa-diene ring, is similar to its Cl and Br ortho-rhom-bic homologues. The observed Pt-I bond distances of 2.6094?(5) and 2.6130?(5)?Å are in the expected range for PtI(2) complexes. The C=C double bonds in the mol-ecule differ significantly [1.373?(10) and 1.403?(10)?Å]. As expected for a platinum(II) complex, the Pt(II) atom is in a square-planar environment (?Pt(?)= 359.71°).

SUBMITTER: Thibault MH 

PROVIDER: S-EPMC2970000 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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(η-Cyclo-octa-1,5-diene)diiodidoplatinum(II).

Thibault Marie-Hélène MH   Fontaine Frédéric-Georges FG  

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9

The monoclinic title complex, [PtI(2)(C(8)H(12))], characterized by a twisted cyclo-octa-diene ring, is similar to its Cl and Br ortho-rhom-bic homologues. The observed Pt-I bond distances of 2.6094 (5) and 2.6130 (5) Å are in the expected range for PtI(2) complexes. The C=C double bonds in the mol-ecule differ significantly [1.373 (10) and 1.403 (10) Å]. As expected for a platinum(II) complex, the Pt(II) atom is in a square-planar environment (ΣPt(α)= 359.71°). ...[more]

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