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2-[(Pyridin-3-yl-amino)-meth-yl]phenol.

ABSTRACT: In the title compound, C(12)H(12)N(2)O, the aromatic rings at either ends of the -CH(2)-NH- link are twisted by 68.79 (7)°. In the crystal, the hy-droxy substituent is a hydrogen-bond donor to the N atom of the pyridine ring of an adjacent mol-ecule, and the hydrogen bond generates a chain along the b axis; it is also a hydrogen-bond acceptor to the amino group of another adjacent mol-ecule. The two hydrogen bonds lead to the formation of a layer structure.

SUBMITTER: Xu J

PROVIDER: S-EPMC3238919 | biostudies-literature |

REPOSITORIES: biostudies-literature

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2-{[(Pyridin-2-yl)amino]-meth-yl}phenol.

Project description:The planes of the aromatic rings of the title compound, C(12)H(12)N(2)O, are twisted by 50.33 (15)°. The phenol O atom is a hydrogen-bond donor to the pyridine N atom, resulting in the formation of an eight-membered ring in the mol-ecule. The amino N atom is a hydrogen-bond donor to the phenol O atom of an adjacent mol-ecule; this hydrogen bond leads to the formation of a helical chain that runs along the a axis.

| S-EPMC3414928 | biostudies-literature

(E)-2-{[(2-Amino-pyridin-3-yl)imino]-meth-yl}-4,6-di-tert-butyl-phenol.

Project description:In the title compound, C(20)H(27)N(3)O, the hy-droxy group forms an intra-molecular O-H⋯N hydrogen bond with the imino N atom. The dihedral angle between the aromatic rings is 33.09 (9)°. In the crystal, mol-ecules form centrosymmetric dimers via pairs of N-H⋯N hydrogen bonds involving amino-pyridine fragments.

| S-EPMC3414959 | biostudies-literature

3-[(E)-(Pyridin-3-yl-imino)-meth-yl]phenol.

Project description:Two independent mol-ecules are present in the asymmetric unit of the title compound, C(12)H(10)N(2)O, in which the 3-hy-droxy-benzaldehyde and the pyridin-3-amine units are almost planar [r.m.s. deviations of 0.0236 and 0.0116Å, respectively, in one mol-ecule and 0.0245 and 0.0162Å, respectively, in the other] and are oriented at dihedral angles of 7.21 (7) and 14.77 (7)°. In the crystal, mol-ecules of the same type form inversion dimers via pairs of O-H⋯N hydrogen bonds, forming R(2) (2)(20) ring motifs. There exist π-π inter-actions between the benzene and pyridine rings of molecules of the same type with centroid-centroid distances of 3.7127 (10) and 3.8439 (10) Å.

| S-EPMC3393889 | biostudies-literature

2-[(5-Chloro-pyridin-2-yl-imino)-meth-yl]phenol.

Project description:In the title compound, C12H9ClN2O, the dihedral angle between the aromatic rings is 1.78 (4)° and an intra-molecular O-H⋯N hydrogen bond closes an S(6) ring. In the crystal, C-H⋯O and C-H⋯N hydrogen bonds connect the mol-ecules into [001] chains.

| S-EPMC9462149 | biostudies-literature

2-{[2-(Pyridin-4-yl)-1H-benzimidazol-1-yl]meth-yl}phenol.

Project description:In the title compound, C19H15N3O, the benzimidazole ring system makes dihedral angles of 44.36?(7) and 75.67?(7)° with the pyridine and benzene rings, respectively. In the crystal, phenolic O-H?N hydrogen bonds to benzimidazole N-atom acceptors give rise to a chain extending along [011].

| S-EPMC3648236 | biostudies-literature

2-Fluoro-6-[(E)-(pyridin-2-yl)imino-meth-yl]phenol.

Project description:The title compound, C(12)H(9)FN(2)O, is almost planar (r.m.s. deviation for the 16 non-H atoms = 0.019?Å), a conformation stabilized by an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring. In the crystal, inversion dimers linked by pairs of C-H?O hydrogen bonds generate R(2) (2)(16) loops.

| S-EPMC3239042 | biostudies-literature

4-Bromo-2-{[(pyridin-3-ylmeth-yl)imino]-meth-yl}phenol.

Project description:The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intra-molecular O-H⋯N hydrogen bonding between the hy-droxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the mol-ecules are stacked in columns along the c axis and several inter-molecular π-π inter-actions are present between the six-membered rings, with a shortest centroid-centroid distance of 3.707 (2) Å.

| S-EPMC3051591 | biostudies-literature

2-[(Pyrimidin-2-yl-amino)-meth-yl]phenol.

Project description:In the title compound, C(11)H(11)N(3)O, the aromatic rings at either ends of the -CH(2)-NH- link are twisted by 72.58 (8)°; the hy-droxy substituent is a hydrogen-bond donor to an N atom of the pyrimidine ring. The other N atom of the pyrimidine ring is a hydrogen-bond acceptor to the amino group of an inversion-related mol-ecule.

| S-EPMC3238918 | biostudies-literature

2-{[(Pyrazin-2-yl)amino]-meth-yl}phenol.

Project description:The two aromatic rings of the title compound, C(11)H(11)N(3)O, are nearly perpendicular to one another, with a dihedral angle between their planes of 80.52 (18)°. In the crystal, the amino N atom is a hydrogen-bond donor to the pyrazine N(1) atom of an inversion-related mol-ecule and the hy-droxy O atom is a hydrogen-bond donor to the pyrazine N(4) atom of another mol-ecule. The two hydrogen bonds lead to the formation of a helical chain that runs along the b axis.

| S-EPMC3414927 | biostudies-literature

2-[(Adamantan-1-yl-amino)-meth-yl]phenol.

Project description:The asymmetric unit of the title compound, C(17)H(23)NO, contains two independent mol-ecules. In both mol-ecules, the hy-droxy group is involved in the formation of an intra-molecular O-H⋯N hydrogen bond. In the crystal, there are two crystallographically independent chains of the mol-ecules propagating along the c axis and formed by weak inter-molecular N-H⋯O hydrogen bonds.

| S-EPMC3274986 | biostudies-literature

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