Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

2-{[(Pyrazin-2-yl)amino]-meth-yl}phenol.

ABSTRACT: The two aromatic rings of the title compound, C(11)H(11)N(3)O, are nearly perpendicular to one another, with a dihedral angle between their planes of 80.52 (18)°. In the crystal, the amino N atom is a hydrogen-bond donor to the pyrazine N(1) atom of an inversion-related mol-ecule and the hy-droxy O atom is a hydrogen-bond donor to the pyrazine N(4) atom of another mol-ecule. The two hydrogen bonds lead to the formation of a helical chain that runs along the b axis.

SUBMITTER: Gao S

PROVIDER: S-EPMC3414927 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

2-[(2-Hy-droxy-benz-yl)amino]-pyrazinium perchlorate-2-[(pyrazin-2-yl-amino)-meth-yl]phenol (1/1).

Project description:In the crystal structure of the title co-crystal, C(11)H(12)N(3)O(+)·ClO(4) (-)·C(11)H(11)N(3)O, the perchlorate ion is disordered about a twofold rotation axis with the Cl atom located on the twofold rotation axis; the 2-[(2-hy-droxy-benz-yl)amino]-pyrazinium cation and the neutral 2-[(pyrazin-2-yl-amino)-meth-yl]phenol mol-ecule are disordered about the rotation axis in a 1:1 ratio. These two are connected by a pyrazine-pyrazine N(1)-H⋯N(4) hydrogen bond. The cation, whose two aromatic rings are twisted along the -CH(2)-NH- bond by 76.8 (1)°, is a hydrogen-bond donor to the perchlorate ion through the N atom of this link.

| S-EPMC3414930 | biostudies-literature

catena-Poly[[silver(I)-?-2-[(pyrazin-2-yl-?(2)N(1):N(4))amino-meth-yl]phenol] nitrate].

Project description:The Ag(I) atom in the polycationic salt, {[Ag(C(11)H(11)N(3)O)]NO(3)}(n), shows a linear coordination [N-Ag-N = 175.0?(2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO(3) (-) counter-ions surround the polymeric chain and inter-act only weakly with it [Ag?O = 2.701?(4) and 2.810?(5)?Å]. Adjacent chains are linked into a three-dimensional network by O-H?O and N-H?O hydrogen bonds.

| S-EPMC3435594 | biostudies-literature

2-[(Pyridin-3-yl-amino)-meth-yl]phenol.

Project description:In the title compound, C(12)H(12)N(2)O, the aromatic rings at either ends of the -CH(2)-NH- link are twisted by 68.79 (7)°. In the crystal, the hy-droxy substituent is a hydrogen-bond donor to the N atom of the pyridine ring of an adjacent mol-ecule, and the hydrogen bond generates a chain along the b axis; it is also a hydrogen-bond acceptor to the amino group of another adjacent mol-ecule. The two hydrogen bonds lead to the formation of a layer structure.

| S-EPMC3238919 | biostudies-literature

2-[(Pyrimidin-2-yl-amino)-meth-yl]phenol.

Project description:In the title compound, C(11)H(11)N(3)O, the aromatic rings at either ends of the -CH(2)-NH- link are twisted by 72.58 (8)°; the hy-droxy substituent is a hydrogen-bond donor to an N atom of the pyrimidine ring. The other N atom of the pyrimidine ring is a hydrogen-bond acceptor to the amino group of an inversion-related mol-ecule.

| S-EPMC3238918 | biostudies-literature

2-{[(Pyridin-2-yl)amino]-meth-yl}phenol.

Project description:The planes of the aromatic rings of the title compound, C(12)H(12)N(2)O, are twisted by 50.33 (15)°. The phenol O atom is a hydrogen-bond donor to the pyridine N atom, resulting in the formation of an eight-membered ring in the mol-ecule. The amino N atom is a hydrogen-bond donor to the phenol O atom of an adjacent mol-ecule; this hydrogen bond leads to the formation of a helical chain that runs along the a axis.

| S-EPMC3414928 | biostudies-literature

2-[(Adamantan-1-yl-amino)-meth-yl]phenol.

Project description:The asymmetric unit of the title compound, C(17)H(23)NO, contains two independent mol-ecules. In both mol-ecules, the hy-droxy group is involved in the formation of an intra-molecular O-H⋯N hydrogen bond. In the crystal, there are two crystallographically independent chains of the mol-ecules propagating along the c axis and formed by weak inter-molecular N-H⋯O hydrogen bonds.

| S-EPMC3274986 | biostudies-literature

2-[(4-Chloro-phenyl)-amino-meth-yl]phenol.

Project description:In the title mol-ecule, C(13)H(12)ClNO, the two benzene rings are twisted from each other by a dihedral angle of 68.60 (8)°. In the crystal structure, the hy-droxy and amino H atoms are involved in inter-molecular hydrogen bonds, O-H⋯N and N-H⋯O, respectively, resulting in R(4) (4)(8) loops about inversion centers.

| S-EPMC3200954 | biostudies-literature

2-[(E)-(2-Amino-phen-yl)imino-meth-yl]-5-(dimethyl-amino)phenol.

Project description:The mol-ecule of the title compound, C(17)H(21)N(3)O, displays a trans configuration with respect to the C=N double bond. The dihedral angle between the planes of the two benzene rings is 50.96?(11)° and a strong intra-molecular O-H?N hydrogen bond is present. An inter-molecular N-H?O hydrogen-bonding inter-action stabilizes the crystal structure.

| S-EPMC2969689 | biostudies-literature

4-{[1-(4-Bromo-phen-yl)eth-yl]amino-meth-yl}phenol.

Project description:The title compound, C(15)H(16)BrNO, obtained from a two-step reaction, was prepared for use in transition metal chemistry as a phenolic ligand with bulky substituents. Inter-molecular N-H?O and O-H?N hydrogen bonds are present in the crystal structure.

| S-EPMC3213552 | biostudies-literature

2-[1-({2-[1-(2-Hy-droxy-5-{[meth-yl(phen-yl)amino]-meth-yl}phen-yl)ethyl-idene-amino]-eth-yl}imino)-eth-yl]-4-{[meth-yl(phen-yl)amino]-meth-yl}phenol.

Project description:Mol-ecules of the title compound, C(34)H(38)N(4)O(2), lie across crystallographic inversion centres. The crystal packing can be described by alternating zigzag chains along the c axis in which the molecules are linked by van der Waals interactions. There is an intra-molecular O-H?N hydrogen bond and the two benzene rings in the asymmetric unit make a dihedral angle of 79.81?(6)°.

| S-EPMC3344659 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data