Unknown

Dataset Information

0

Bis[1-(eth-oxy-carbonyl-meth-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato-?(2)S,S')nickelate(II).

ABSTRACT: The asymmetric unit of the title ion-pair complex, (C(9)H(12)NO(2))(2)[Ni(C(4)N(2)S(2))(2)], contains two 1-(eth-oxy-carbonyl-meth-yl)pyridinium cations and one bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dianion, which exhibits a slightly distorted square-planar coordination geometry. In the crystal, the cations are linked by strong C-H?O hydrogen bonds into C(6) chains along [100]. The cations and anions are linked into a three-dimensional architecture by weak C-H?N and C-H?S inter-actions.

SUBMITTER: Ren TL 

PROVIDER: S-EPMC3435580 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis[1-(eth-oxy-carbonyl-meth-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κ(2)S,S')nickelate(II).

Ren Tian-Li TL   Yang Cheng-Jian CJ   Fang De-Yu DY   Shi Guo-Xun GX   Zhu Xue X  

Acta crystallographica. Section E, Structure reports online 20120804 Pt 9

The asymmetric unit of the title ion-pair complex, (C(9)H(12)NO(2))(2)[Ni(C(4)N(2)S(2))(2)], contains two 1-(eth-oxy-carbonyl-meth-yl)pyridinium cations and one bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dianion, which exhibits a slightly distorted square-planar coordination geometry. In the crystal, the cations are linked by strong C-H⋯O hydrogen bonds into C(6) chains along [100]. The cations and anions are linked into a three-dimensional architecture by weak C-H⋯N and C-H⋯S inter-a  ...[more]

Similar Datasets

Unknown 1-Butyl-pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(III).
| S-EPMC3246985 | biostudies-literature
Unknown Bis[1-(3-cyano-benz-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC3050285 | biostudies-literature
Unknown 1-(2-Fluoro-benzyl-ideneamino)pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC2977634 | biostudies-literature
Unknown Bis[1-(4-cyano-benz-yl)pyrazinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC3152075 | biostudies-literature
Unknown Bis(3,5,7-triaza-1-azoniatricyclo-[3.3.1.1]deca-ne) bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC3120553 | biostudies-literature
Unknown Bis(1-amino-4-methyl-pyridinium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato-?S,S')nickelate(II).
| S-EPMC2961888 | biostudies-other
Unknown Bis(4-dimethyl-amino-1-ethyl-pyridinium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato-?(2)S,S')nickelate(II).
| S-EPMC3343807 | biostudies-other
Unknown Bis(4-cyano-1-methyl-pyridinium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato-?S,S')cuprate(II).
| S-EPMC3274894 | biostudies-other
Unknown Bis(8-hy-droxy-1-methyl-quinolin-1-ium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dihydrate.
| S-EPMC3238595 | biostudies-other
Unknown Hexa-kis-(dimethyl sulfoxide-?O)nickel(II) bis-(2,2-dicyano-ethene-1,1-dithiol-ato-?S,S')nickelate(II).
| S-EPMC3254330 | biostudies-literature