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(E)-4-Chloro-2-{[4-(3,5-dichloro-pyridin-2-yl-oxy)phenyl-imino]-meth-yl}phenol.

ABSTRACT: In the title mol-ecule, C(18)H(11)Cl(3)N(2)O(2), the central benzene ring is oriented at 8.44?(12) and 70.57?(11)° with respect to the terminal chloro-phenol and dichloro-pyridine rings, respectively. The mol-ecular structure is stabilized by an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring motif. In the crystal, ?-? stacking between parallel pyridine rings is observed [centroid-centroid distance = 3.6561?(14)?Å].

SUBMITTER: Ji HB

PROVIDER: S-EPMC3247386 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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(E)-4-Chloro-2-{[4-(3,5-dichloro-pyridin-2-yl-oxy)phenyl-imino]-meth-yl}phenol.

Ji Hong-Bo HB Zhang Pei-Zhi PZ Wu Jun J

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

In the title mol-ecule, C(18)H(11)Cl(3)N(2)O(2), the central benzene ring is oriented at 8.44 (12) and 70.57 (11)° with respect to the terminal chloro-phenol and dichloro-pyridine rings, respectively. The mol-ecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring motif. In the crystal, π-π stacking between parallel pyridine rings is observed [centroid-centroid distance = 3.6561 (14) Å]. ...[more]

PMID: 22220004

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