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4-Methyl-N-(3-methyl-phen-yl)pyridin-2-amine.

ABSTRACT: The title amine, C(13)H(14)N(2), is twisted with a dihedral angle between the rings of 60.07?(9)°. The amine N-H group and pyridine N atom are syn allowing for the formation of centrosymmetric eight-membered {?HNCN}(2) synthons via N-H?N hydrogen bonds. The two-mol-ecule aggregates are sustained in the three-dimensional crystal packing via C-H?? and ?-? inter-actions [centroid-centroid distance for pyridyl rings = 3.7535?(12)?Å].

SUBMITTER: Fairuz ZA

PROVIDER: S-EPMC3247467 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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4-Methyl-N-(3-methyl-phen-yl)pyridin-2-amine.

Fairuz Zainal Abidin ZA Aiyub Zaharah Z Abdullah Zanariah Z Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

The title amine, C(13)H(14)N(2), is twisted with a dihedral angle between the rings of 60.07 (9)°. The amine N-H group and pyridine N atom are syn allowing for the formation of centrosymmetric eight-membered {⋯HNCN}(2) synthons via N-H⋯N hydrogen bonds. The two-mol-ecule aggregates are sustained in the three-dimensional crystal packing via C-H⋯π and π-π inter-actions [centroid-centroid distance for pyridyl rings = 3.7535 (12) Å]. ...[more]

PMID: 22220085

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