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3-(Trimethyl-sil-yl)prop-2-ynyl p-toluene-sulfonate.

ABSTRACT: In the title compound, C(13)H(18)O(3)SSi, the SO(3) group displays a partial rotational (ca 50°) disorder about the C-S bond, with relative proportions 0.7744?(13):0.2256?(13). This disorder also forces the propynyl CH(2) group to be disordered.

SUBMITTER: Schmitt DC

PROVIDER: S-EPMC3247495 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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3-(Trimethyl-sil-yl)prop-2-ynyl p-toluene-sulfonate.

Schmitt Devin C DC Morales Guillermo A GA Fronczek Frank R FR Watkins Steven F SF

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title compound, C(13)H(18)O(3)SSi, the SO(3) group displays a partial rotational (ca 50°) disorder about the C-S bond, with relative proportions 0.7744 (13):0.2256 (13). This disorder also forces the propynyl CH(2) group to be disordered. ...[more]

PMID: 22220113

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