Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N-(1-Naphth-yl)benzene-sulfonamide.

ABSTRACT: In the title compound, C(16)H(13)NO(2)S, the C-SO(2)-NH-C torsion angle is -70.1?(2)°. The dihedral angle between the planes of the naphthyl ring system and the phenyl ring is 34.67?(4)°. In the crystal, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds into chains along [100]. There are also ?-? inter-actions between adjacent naphthyl groups [inter-planar spacing = 3.541?(3)?Å] for mol-ecules stacked along [100].

SUBMITTER: Zhang S

PROVIDER: S-EPMC3247570 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

N-(1-Naphth-yl)benzene-sulfonamide.

Zhang Sifang S Zhang Yuewen Y Wang Chuntao C Zhu Ruitao R

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

In the title compound, C(16)H(13)NO(2)S, the C-SO(2)-NH-C torsion angle is -70.1 (2)°. The dihedral angle between the planes of the naphthyl ring system and the phenyl ring is 34.67 (4)°. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds into chains along [100]. There are also π-π inter-actions between adjacent naphthyl groups [inter-planar spacing = 3.541 (3) Å] for mol-ecules stacked along [100]. ...[more]

PMID: 22219875

Similar Datasets

N-[3-(Benzene-sulfonamido)-prop-yl]benzene-sulfonamide.

Project description:In the title compound, C(15)H(18)N(2)O(4)S(2), the dihedral angle between the aromatic rings is 71.8?(2)°. The conformation of the central N-C-C-C-N fragment is gauche-gauche [torsion angles = 72.5?(5) and 65.7?(5)°]. Both N atoms adopt pyramidal geometries. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds, generating (001) sheets, and weak C-H?O inter-actions consolidate the packing.

| S-EPMC3151767 | biostudies-literature

1,4-Bis{(+)-(S)-[1-(1-naphth-yl)eth-yl]imino-meth-yl}benzene.

Project description:The title compound, C(32)H(28)N(2), is a chiral bis-imine in which both imine groups display the common E configuration. The naphthyl groups present different orientations with respect to the central core, as reflected in the dihedral angles of 21.4?(2) and 78.83?(14)° between the benzene and naphthyl mean planes, thus the highest possible C(2) local molecular symmetry is not attained. This C(1) mol-ecular conformation allows multiple C-H?? inter-molecular contacts involving all aromatic rings, while no ?-? inter-actions are available for the stabilization of the crystal structure. The resulting packing structure is based on mol-ecules stacked along [100].

| S-EPMC2970175 | biostudies-literature

4-[(1,3-Dioxoisoindolin-2-yl)meth-yl]benzene-sulfonamide.

Project description:The title compound, C15H12N2O4S, is V-shaped with the isoindoline ring system (r.m.s. deviation = 0.006 Å) inclined to the benzene ring by 84.27 (13)°. In the crystal, inversion dimers are formed via pairwise N-H⋯O hydrogen bonds. These dimers associate further into corrugated ribbons, via pairwise N-H⋯O and C-H⋯O hydrogen bonds, propagating along the a-axis direction and lying parallel to (001).

| S-EPMC3998451 | biostudies-literature

N-(2,4-Dichloro-phen-yl)benzene-sulfonamide.

Project description:The title compound, C(12)H(9)Cl(2)NO(2)S, crystallizes with two independent mol-ecules in the asymmetric unit. The dihedral angles between the two aromatic rings are 70.8?(1) and 74.8?(1)° for the two mol-ecules. The crystal structure features dimers made up of one each of the two asymmetric molecules linked by pairs of N-H?O hydrogen bonds. An intra-molecular N-H?Cl hydrogen bond is also observed in both mol-ecules.

| S-EPMC2980121 | biostudies-literature

N-(3,4-Dimethyl-phen-yl)benzene-sulfonamide.

Project description:The structure of the title compound, C(14)H(15)NO(2)S, shows the sulfonamide N atom to be approximately perpendicular to the plane through the S-bound benzene ring [the N-S-C-C torsion angle is -87.4?(3)°] and to lie to the opposide side of this ring to the two sulfonamide O atoms. The N-bound benzene ring is splayed out with respect to the rest of the mol-ecule so that overall, the mol-ecule adopts a twisted conformation. The dihedral angle between the two benzene rings is 64.5?(3)°. In the crystal, supra-molecular chains aligned along the b axis are formed via N-H?O hydrogen bonds.

| S-EPMC3007249 | biostudies-literature

N-(3-Chloro-benzo-yl)benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(13)H(10)ClNO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The dihedral angle between the two benzene rings is 87.5?(1)°. The crystal structure features inversion-related dimers linked by pairs of N-H?O(S) hydrogen bonds.

| S-EPMC2971321 | biostudies-literature

N-(2-Acetyl-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(14)H(13)NO(3)S, the phenyl ring makes a dihedral angle of 81.5?(1)° with the benzene ring. The mol-ecular structure is stabilized by an intra-molecular N-H?O hydrogen bond and weak C-H?O inter-actions. In the crystal structure, mol-ecules are linked by weak inter-molecular C-H?O and C-H?? inter-actions.

| S-EPMC2970053 | biostudies-literature

N-(2,5-Dichloro-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(12)H(9)Cl(2)NO(2)S, the conformation of the N-H bond is syn to the 2-chloro group and anti to the 3-chloro group of the aniline benzene ring. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of 66.4?(2)°. The two rings form a dihedral angle of 73.3?(1)° and an intra-molecular N-H?Cl hydrogen bond occurs. The crystal structure features chains linked by N-H?O hydrogen bonds.

| S-EPMC2983589 | biostudies-literature

N-(2,6-Dimethyl-phen-yl)benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(14)H(15)NO(2)S, the N-H bond is trans to one of the S=O double bonds, similar to what is observed in N-(2-methyl-phen-yl)benzene-sulfonamide and other aryl sulfonamides. The two aromatic rings enclose a dihedral angle of 44.9?(1)°. The mol-ecules are connected by inter-molecular N-H?O hydrogen bonds into chains running along the a axis. An intermolecular C-H?O hydrogen bond is also present.

| S-EPMC2960643 | biostudies-literature

N-(3-Chloro-phen-yl)benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(12)H(10)ClNO(2)S, the N-H bond is trans to one of the S=O bonds. The two aromatic rings form a dihedral angle of 65.4?(1)°, compared with a value of 49.1?(1)° in N-(2-chloro-phen-yl)-benzene-sulfonamide. The mol-ecules are connected by inter-molecular N-H?O hydrogen bonds into chains running along the b axis.

| S-EPMC2960722 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data