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Catena-Poly[[bis-(?-2-formyl-6-meth-oxy-phenolato-1:2?O,O:O,O)copper(II)sodium]-?-tetra-fluorido-borate-1:1'?F:F'].

ABSTRACT: In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-meth-oxy-phenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetra-fluoridoborate anions. The tetra-fluoridoborate anion links the Na(+) ions, forming a one-dimensional structure along [001]. Three F atoms of the tetra-fluoridoborate anion are disordered over two sets of sites, with an occupancy ratio of 0.790?(11):0.210?(11).

SUBMITTER: Yang Y

PROVIDER: S-EPMC3254308 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(μ-2-formyl-6-meth-oxy-phenolato-1:2κO,O:O,O)copper(II)sodium]-μ-tetra-fluorido-borate-1:1'κF:F'].

Yang Yu Y Gao Po P Yang Jing-Lin JL Hou Hai-Ge HG Gao Ting T

Acta crystallographica. Section E, Structure reports online 20111210 Pt 1

In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-meth-oxy-phenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetra-fluoridoborate anions. The tetra-fluoridoborate anion links the Na(+) ions, forming a one-dimensional structure along [001]. Three F atoms of the tetra-fluoridoborate anion are disordered ov ...[more]

PMID: 22259338

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