Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[tribenzyl-tin(IV)]-?-4-formyl-2-meth-oxy-6-nitro-phenolato-?O:O].

ABSTRACT: The formyl-meth-oxy-nitro-phenoxide ions in the polymeric title compound, [Sn(C(7)H(7))(3)(C(8)H(6)NO(5))](n), link adjacent triorganotin(IV) cations into linear chains lying close to (101) [Sn-O = 2.1227?(12)?Å and Sn? O = 2.4936?(13)?Å]. The Sn(IV) atom is displaced out of the C(3)Sn girdle of the trans-C(3)SnO(2) trigonal-bipyramidal polyhedron in the direction of the covalently-bonded O atom [Sn-O-C = 137.63?(11)°] by 0.247?(1)?Å; the geometry is distorted towards an octa-hedron by a remote O atom of the meth-oxy subsituent [Sn?O = 3.019?(1)?Å].

SUBMITTER: Keng TC

PROVIDER: S-EPMC3120579 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[[tribenzyl-tin(IV)]-μ-4-formyl-2-meth-oxy-6-nitro-phenolato-κO:O].

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The formyl-meth-oxy-nitro-phenoxide ions in the polymeric title compound, [Sn(C(7)H(7))(3)(C(8)H(6)NO(5))](n), link adjacent triorganotin(IV) cations into linear chains lying close to (101) [Sn-O = 2.1227 (12) Å and Sn← O = 2.4936 (13) Å]. The Sn(IV) atom is displaced out of the C(3)Sn girdle of the trans-C(3)SnO(2) trigonal-bipyramidal polyhedron in the direction of the covalently-bonded O atom [Sn-O-C = 137.63 (11)°] by 0.247 (1) Å; the geometry is distorted towards an octa-hedron by a remote ...[more]

PMID: 21754610

Similar Datasets

catena-Poly[[tribenzyl-tin(IV)]-?-4-nitro-cinnamato-?O:O'].

Project description:The 4-nitro-cinnamate anion in the title compound, [Sn(C(7)H(7))(3)(C(9)H(6)NO(4))](n), bridges adjacent tribenzyl-tin cations into a helical chain running along the b axis. The Sn atoms in the two independent mol-ecules adopt distorted trans-C(3)SnO(2) trigonal-bipyramidal geometries. The repeat distance of the polymeric chain is b/2.

| S-EPMC2959618 | biostudies-literature

catena-Poly[[bis-(μ-2-formyl-6-meth-oxy-phenolato)copper(II)sodium]-μ-nitrato].

Project description:In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(NO(3))](n), the Cu(II) ion is five-coordinated in a square-pyramidal arrangement by four atoms of two different ligand molecules in equatorial positions and one remote nitrate O atom in the apical position. The Na(+) ion is eight-coordinated by four ligand O atoms and four nitrate O atoms. The ligand links the Cu(II) and Na ions, forming a layered arrangement extending parallel to (001).

| S-EPMC3246950 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-?-(E)-3-phenyl-prop-2-enoato-?O:O'].

Project description:The Sn(IV) atom in the title carboxyl-ate-bridged polymer, [Sn(C(7)H(7))(3)(C(9)H(7)O(2))](n), exists in a trans-C(3)SnO(2) trigonal-bipyramidal geometry (average covalent Sn-O = 2.167?Å, average dative Sn-O = 2.361?Å and average O-Sn-O = 169.6°). The polymer propagates as a helical chain along the b axis with a repeat distance that is half the b-axial length. There are four independent formula units in the asymmetric unit; two are disposed about a false center of inversion with respect to the other two so that the space group emulates a centric space group.

| S-EPMC3120586 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-?-2-(piperidin-1-ylcarbothio-ylsulfan-yl)acetato-?O:O'].

Project description:The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl-ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O(covalent) bond by 0.093?(4)?Å and in the second mol-ecule, the Sn atom is displaced by 0.105?(4)?Å in the same direction.

| S-EPMC2983362 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-μ-(E)-3-(2-fur-yl)prop-2-enoato-κO:O'].

Project description:In the title carboxyl-ate-bridged polymer, [Sn(C(7)H(7))(3)(C(7)H(5)O(3))](n), the Sn(IV) atom exists in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry. The polymer propagates as a chain along the a axis. There are two independent formula units in the asymmetric unit; the furyl ring of one of the anions is disordered over two positions in a 0.630 (8):0.370 (8) ratio. The crystal studied was a non-merohedral twin with a minor twin domain of 37.3 (1)%.

| S-EPMC3151990 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-quinaldato].

Project description:The title compound, [Sn(CH(3))(3)(C(10)H(6)NO(2))](n), forms an extended one-dimensional chain structure. There are two independent Sn(IV) ions, both of which are in slightly distorted trigonal-bipyramidal coordination environments with two symmetry-related O atoms in the axial sites. In each case, the Sn(IV) ion and one of the three equatorial C atoms lie on a crystallographic twofold axis.

| S-EPMC2914916 | biostudies-literature

catena-Poly[[bis-(?-2-formyl-6-meth-oxy-phenolato-1:2?O,O:O,O)copper(II)sodium]-?-tetra-fluorido-borate-1:1'?F:F'].

Project description:In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-meth-oxy-phenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetra-fluoridoborate anions. The tetra-fluoridoborate anion links the Na(+) ions, forming a one-dimensional structure along [001]. Three F atoms of the tetra-fluoridoborate anion are disordered over two sets of sites, with an occupancy ratio of 0.790?(11):0.210?(11).

| S-EPMC3254308 | biostudies-literature

catena-Poly[[triphenyl-tin(IV)]-?-5-amino-2-nitro-benzoato-?O:O].

Project description:The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal-bipyramidal geometry by two monodentate carboxyl-ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxyl-ate groups [O-Sn-O = 170.88?(3)°]. The benzene ring of the 5-amino-2-nitro-benzoate ligand forms dihedral angles of 82.92?(6), 81.10?(6) and 83.54?(6)° with respect to the three phenyl rings. In the crystal, the chains are linked by inter-molecular N-H?O and weak C-H?O inter-actions into a three-dimensional network. The crystal structure is further stabilized by weak inter-molecular C-H?? inter-actions.

| S-EPMC3200871 | biostudies-other

catena-Poly[[trimethyl-tin(IV)]-?-2-phenyl-butano-ato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(10)H(11)O(2))](n), the Sn atom has a distorted trigonal-bipyramidal coordination geometry, with two O atoms of two symmetry-related carboxyl-ate ligands in axial positions and three methyl groups in equatorial positions. In the crystal structure, carboxyl-ate bridges link the metal atoms, forming zigzag chains parallel to the b axis.

| S-EPMC3011523 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-phenyl-seleninato-?O:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

| S-EPMC3051585 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data