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Bis(O-ethyl dithio-carbonato-?S,S')bis-(pyridine-3-carbonitrile-?N)nickel(II).

ABSTRACT: The Ni(2+) ion in the title complex, [Ni(C(3)H(5)OS(2))(2)(C(6)H(4)N(2))(2)], is in a strongly distorted octa-hedral coordination environment formed by an N(2)S(4) donor set, with the Ni(2+) ion located on a centre of inversion. In the crystal, weak C-H?S and C-H?N inter-actions are observed.

SUBMITTER: Kapoor S

PROVIDER: S-EPMC3254324 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Bis(O-ethyl dithio-carbonato-κS,S')bis-(pyridine-3-carbonitrile-κN)nickel(II).

Kapoor Sanjay S Kour Ramandeep R Sachar Renu R Kant Rajni R Gupta Vivek K VK Kapoor Kamini K

Acta crystallographica. Section E, Structure reports online 20111217 Pt 1

The Ni(2+) ion in the title complex, [Ni(C(3)H(5)OS(2))(2)(C(6)H(4)N(2))(2)], is in a strongly distorted octa-hedral coordination environment formed by an N(2)S(4) donor set, with the Ni(2+) ion located on a centre of inversion. In the crystal, weak C-H⋯S and C-H⋯N inter-actions are observed. ...[more]

PMID: 22259356

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