Browse
Submit Data
Databases
API
Help

Dataset Information

31 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(1,10-phenanthroline-5,6-dione-?N,N')silver(I) 2-hy-droxy-3,5-dinitro-benzoate.

ABSTRACT: In the cation of the title salt, [Ag(C(12)H(6)N(2)O(2))(2)](C(7)H(3)N(2)O(7)), the Ag(I) atom is coordinated in a distorted tetra-hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro-salicylate anion has only a short contact [2.847?(6)?Å] between one of its O atoms and the Ag(I) atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4?(1)°. There is an intra-molecular O-H?O hydrogen bond in the 3,5-dinitro-salicylate anion.

SUBMITTER: Wang ST

PROVIDER: S-EPMC3254338 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(1,10-phenanthroline-5,6-dione-κN,N')silver(I) 2-hy-droxy-3,5-dinitro-benzoate.

Wang Shen-Tang ST Che Guang-Bo GB Liu Chun-Bo CB Wang Xing X Liu Ling L

Acta crystallographica. Section E, Structure reports online 20111221 Pt 1

In the cation of the title salt, [Ag(C(12)H(6)N(2)O(2))(2)](C(7)H(3)N(2)O(7)), the Ag(I) atom is coordinated in a distorted tetra-hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro-salicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the Ag(I) atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intra-molecular O-H⋯O hydrogen bond in the 3,5-dinitro-salicylate ...[more]

PMID: 22259371

Similar Datasets

2-Hy-droxy-anilinium 3,5-dinitro-benzoate.

Project description:In the title molecular salt, C(6)H(8)NO(+)·C(7)H(3)N(2)O(6) (-), which crystallizes in the chiral monoclinic space group P2(1), the achiral components assemble by three different N-H⋯O, one O-H⋯O and one C-H⋯O hydrogen bonds into two-stranded chains running parallel to [010]. The dihedral angles between the carboxy group and the two nitro groups and the mean plane of their attached benzene ring are 24.5 (9), 6.1 (6) and 13.0 (1)°, respectively..

| S-EPMC3344637 | biostudies-literature

Acetato(1,10-phenanthroline-5,6-dione)silver(I) trihydrate.

Project description:In the structure of the title compound, [Ag(C(2)H(3)O(2))(C(12)H(6)N(2)O(2))]·3H(2)O, the Ag(I) atom is coordinated by both 1,10-phenanthroline-5,6-dione N atoms and one O atom from the acetate anion. The three water mol-ecules are involved in extensive hydrogen bonding to each other and to the acetate O and 1,10-phenanthroline-5,6-dione O atoms. In addition, there are weak C-H⋯O inter-actions.

| S-EPMC2960336 | biostudies-literature

2-(2,4-Dinitro-benz-yl)pyridinium 2-hy-droxy-3,5-dinitro-benzoate.

Project description:In the structure of the title salt, C(12)H(10)N(3)O(4) (+)·C(7)H(3)N(2)O(7) (-), the cations and the anions are linked by a single N(+)-H?O(carbox-yl) hydrogen bond, the discrete cation-anion unit having no inter-molecular associations other than weak cation-anion aromatic ring ?-? inter-actions [ring centroid separation = 3.7320?(14)?Å] and a number of weak inter-unit aromatic C-H?O contacts. An intramolecular C-H?O hydrox-yl-carboxyl hydrogen bond occurs in the anion.

| S-EPMC3007337 | biostudies-literature

2-Amino-4-methylpyridinium 2-hy-droxy-3,5-dinitro-benzoate.

Project description:In the anion of the title mol-ecular salt, C(6)H(9)N(2) (+)·C(7)H(3)N(2)O(7) (-), the two nitro groups are twisted from the attached benzene ring with dihedral angles of 27.36?(10) and 4.86?(11)°. The anion is stabilized by an intra-molecular O-H?O hydrogen bond, which generates an S(6) ring motif. In the crystal, the cations and anions are linked by N-H?O and C-H?O inter-actions and are further consolidated by C-H?? inter-actions, to generate a three-dimensional network. A short O?N contact of 2.876?(2)?Å also occurs.

| S-EPMC3007456 | biostudies-literature

Bis(1,10-phenanthroline-5,6-dione-κN,N')silver(I) tetra-fluoridoborate.

Project description:In the structure of the title compound, [Ag(C(12)H(6)N(2)O(2))(2)]BF(4) or [AgL(2)]BF(4) (L = phendione), the Ag and B atoms are located on twofold rotation axes. The dihedral angle between the two phendione ligands is 36.7 (2)°. The coordination about the Ag(I) center is distorted tetra-hedral (τ(4) = 0.546). The crystal structure is consolidated by weak C-H⋯O(phendione) and C-H⋯F(BF(4) (-)) inter-actions. The BF(4) (-) counter-anion is strongly disordered and was modelled with two sets of idealized F atoms.

| S-EPMC2969900 | biostudies-literature

1,10-Phenanthroline-5,6-dione ethanol monosolvate.

Project description:In the title compound, C12H6N2O2·C2H5OH, the mol-ecule of the 1,10-phenanthroline-5,6-dione is approximately planar, with a maximum deviation of 0.051?(1)?Å. In the crystal, mol-ecules are linked by O-H?N and weak C-H?O hydrogen bonds, forming supra-molecular chains propagating along [110]. ?-? stacking inter-actions are observed between the pyridine rings of neighbouring chains, the centroid-centroid separations being 3.6226?(11) and 3.7543?(11)?Å.

| S-EPMC4011276 | biostudies-literature

3,3-Dinitro-azetidinium 2-hy-droxy-benzoate.

Project description:In the title gem-dinitro-azetidinium 2-hy-droxy-benzoate salt, C(3)H(6)N(3)O(4) (+)·C(7)H(5)O(3) (-), the azetidine ring is virtually planar, with a mean deviation from the plane of 0.0242?Å. The dihedral angle between the two nitro groups is 87.5?(1)°.

| S-EPMC3009224 | biostudies-literature

Dichloridobis(1,10-phenanthroline-5,6-dione-κN,N')mercury(II).

Project description:In the title compound, [HgCl(2)(C(12)H(6)N(2)O(2))(2)], the Hg(II) atom is located on a twofold rotation axis and exists within a distorted octa-hedral geometry defined by a cis-Cl(2)N(4) donor set. Mol-ecules are connected into layers in the ac plane via extensive C-H⋯Cl contacts as each Cl atom forms two such inter-actions. Contacts between the layers are of the type C=O⋯π [O⋯centroid distance = 3.110 (8) Å].

| S-EPMC2971919 | biostudies-literature

Poly[(μ-2-hy-droxy-3,5-dinitro-benzoato)rubidium].

Project description:The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(7))](n), comprises an Rb(+) cation and a 3,5-dinitro-salicylate ligand. The Rb(+) cation is 10-coordinated by O atoms from eight 3,5-dinitro-salicylate anions and is linked by three μ(2)-O atoms, forming a zigzag chain along the b-axis direction, which is further linked by the phenyl groups, giving the three-dimensional framework. The crystal structure involves intra-anionic O-H⋯O hydrogen bonds and strong π-π stacking inter-actions [centroid-centroid distance = 3.6755 (7) Å].

| S-EPMC3100035 | biostudies-literature

Tetra-aqua-(1,10-phenanthroline-5,6-dione-κN,N')cobalt(II) dinitrate.

Project description:The asymmetric unit of the title compound, [Co(C(12)H(6)N(2)O(2))(H(2)O)(4)](NO(3))(2), consists of a Co(II) complex cation with twofold rotational symmetry and two nitrate anions. The Co(II) atom has a distorted octa-hedral geometry with the basal plane occupied by two 1,10-phenanthroline-5,6-dione N atoms and two aqua O atoms, with the other two aqua ligands in axial positions. The aqua ligands are involved in extensive hydrogen bonding to nitrate and 1,10-phenanthroline-5,6-dione O atoms.

| S-EPMC2969730 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data