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Tris(1,10-phenanthroline-5,6-dione-?N,N')zinc bis-(perchlorate) acetonitrile monosolvate.

ABSTRACT: In the title compound, [Zn(C(12)H(6)N(2)O(2))(3)](ClO(4))(2)·CH(3)CN, the Zn(II) atom is coordinated by six N atoms from three chelating 1,10-phenanthroline-5,6-dione ligands in a distorted octa-hedral environment. In the crystal, inter-molecular C-H?O hydrogen bonds and O?? and N?? inter-actions [O?centroid distances = 2.907?(5) and 2.843?(7)?Å; N?centroid distance = 2.861?(10)?Å] link the complex cations, perchlorate anions and acetonitrile solvent mol-ecules into a three-dimensional network.

SUBMITTER: Zhao J 

PROVIDER: S-EPMC3201451 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Tris(1,10-phenanthroline-5,6-dione-κN,N')zinc bis-(perchlorate) acetonitrile monosolvate.

Zhao Jing J   Zhang Heng H   Zhang Zhaozhi Z   Zhao Haiyan H   Zhu Guoyi G  

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title compound, [Zn(C(12)H(6)N(2)O(2))(3)](ClO(4))(2)·CH(3)CN, the Zn(II) atom is coordinated by six N atoms from three chelating 1,10-phenanthroline-5,6-dione ligands in a distorted octa-hedral environment. In the crystal, inter-molecular C-H⋯O hydrogen bonds and O⋯π and N⋯π inter-actions [O⋯centroid distances = 2.907 (5) and 2.843 (7) Å; N⋯centroid distance = 2.861 (10) Å] link the complex cations, perchlorate anions and acetonitrile solvent mol-ecules into a three-dimensional network. ...[more]

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