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Methyl (Z)-2-[(2,4-dioxothia-zolidin-3-yl)meth-yl]-3-(2-methyl-phen-yl)prop-2-enoate.

ABSTRACT: The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thia-zolidine ring is essentially planar [maximum deviation = 0.008?(1)?Å for the N atom] and is oriented at a dihedral angle of 59.1?(1)° with respect to the benzene ring. In the crystal, pairs of C-H?O hydrogen bonds link centrosymmetrically related mol-ecules into dimers, generating R(2) (2)(18) ring motifs. The crystal packing is further stabilized by C-H?? and C-O?? [O?centroid = 3.412?(2)?Å and C-O?centroid = 115.0?(1)°] inter-actions.

SUBMITTER: Vijayakumar S

PROVIDER: S-EPMC3254499 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Methyl (Z)-2-[(2,4-dioxothia-zolidin-3-yl)meth-yl]-3-(2-methyl-phen-yl)prop-2-enoate.

Vijayakumar S S Murugavel S S Kannan D D Bakthadoss M M

Acta crystallographica. Section E, Structure reports online 20111217 Pt 1

The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thia-zolidine ring is essentially planar [maximum deviation = 0.008 (1) Å for the N atom] and is oriented at a dihedral angle of 59.1 (1)° with respect to the benzene ring. In the crystal, pairs of C-H⋯O hydrogen bonds link centrosymmetrically related mol-ecules into dimers, generating R(2) (2)(18) ring motifs. The crystal packing is further stabilized by C-H⋯π and C-O⋯π [O⋯centroid = 3.412 (2) Å and C-O⋯centroid = ...[more]

PMID: 22259442

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