Browse
Submit Data
Databases
API
Help

Dataset Information

18 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(1-Naphthyl-imino-meth-yl)ferrocene.

ABSTRACT: In the title mol-ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo-penta-dienyl rings are approximately eclipsed and the inter-planar angle is 0.8?(7)°. The Fe atom is slightly closer to the substituted cyclo-penta-dienyl ring, with an Fe?centroid distance of 1.639?(2)?Å, compared with 1.645?(2)?Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclo-penta-dienyl ring with a deviation of 10.3?(1)°. The angle formed by the C=N double bond and the naphthal-ene ring system is 47.1?(1)°. The C-N=C-C torsion angle is 177.32?(5)°.

SUBMITTER: Zang Y

PROVIDER: S-EPMC3257069 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(1-Naphthyl-imino-meth-yl)ferrocene.

Zang Yunbo Y

Acta crystallographica. Section E, Structure reports online 20080820 Pt 9

In the title mol-ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo-penta-dienyl rings are approximately eclipsed and the inter-planar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclo-penta-dienyl ring, with an Fe⋯centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclo-penta-dienyl ring with a deviation of 10.3 (1)°. The angle formed by the C=N double bond and the naphthal- ...[more]

PMID: 22247715

Similar Datasets

Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-?N,P}platinum(II) dichloro-methane hemisolvate.

Project description:In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis.

| S-EPMC2968145 | biostudies-literature

(1-Naphthyl-meth-yl)ammonium chloride.

Project description:The reaction of 1-naphthyl-methyl-amine and hydro-chloric acid in a 1:1 molar ratio resulted in the formation of the 1:1 proton-transfer compound, C(11)H(12)N(+)·Cl(-). In the crystal, the ions are linked by N-H?Cl hydrogen bonds into a sheet pattern in the ab plane such that each Cl(-) ion is bonded to three NH groups from the naphthylmethylammonium ion.

| S-EPMC2983625 | biostudies-literature

4-Bromo-2-({4-[(hy-droxy-imino)-meth-yl]phen-yl}imino-meth-yl)phenol.

Project description:In the title compound, C(14)H(11)BrN(2)O(2), the mean planes of the two benzene rings are almost parallel to each other, making a dihedral angle of 4.09?(1)°. An intra-molecular O-H?N hydrogen bond occurs. In the crystal, inter-molecular O-H?N and C-H?O hydrogen bonds link the mol-ecules into a chain-like supra-molecular structure.

| S-EPMC3007216 | biostudies-literature

Bis(2-naphthyl-meth-yl)diphenyl-silane.

Project description:The title compound, C(34)H(28)Si, was prepared as an inter-nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra-hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42?(4)° with one another. A naphthalene system and a phenyl ring are also nearly perpendicular, making an angle of 86.18?(6)° with one another. In the crystal, the mol-ecules pack in columns parallel to the a axis, and exhibit arene C-H??(arene) inter-actions both within and between columns.

| S-EPMC2980158 | biostudies-literature

1-(Diphenyl-phosphinothio-yl)-2-[(4-methyl-phen-yl)meth-oxy-meth-yl]ferrocene.

Project description:Following our continuing inter-est in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C(5)H(5))(C(26)H(24)OPS)], in which there are two nearly identical mol-ecules in the asymmetric unit. The conformation of the cyclo-penta-dienyl (Cp) rings in each ferrocenyl group are inter-mediate between eclipsed and staggered, with twist angles of 16.6?(2) and 8.9?(2)°. The protecting S atom is located endo with respect to the substituted Cp ring. In the crystal, mol-ecules are connected through inter-molecular C-H?? inter-actions.

| S-EPMC3009340 | biostudies-literature

2-[(4-Meth-oxy-benz-yl)imino-meth-yl]phenol.

Project description:In the title Schiff base compound, C(15)H(15)NO(2), prepared from 4-meth-oxy-benzyl-amine and salicyl-aldehyde, an intra-molecular O-H?N hydrogen bonds influences the mol-ecular conformation; the two aromatic rings form a dihedral angle of 73.5?(1)°. In the crystal, weak inter-molecular C-H?O inter-actions link the mol-ecules into chains propagating in [010].

| S-EPMC3011435 | biostudies-literature

4-Methyl-2-[(E)-phen-yl(1,2,3,4-tetra-hydro-1-naphthyl-imino)meth-yl]phenol.

Project description:In the crystal structure of the title compound, C(24)H(23)NO, the phenyl ring makes dihedral angles of 81.53?(11) and 75.35?(12)°, respectively, with the methyl-substituted and the fused benzene rings. The dihedral angle between the two benzene rings is 71.10?(10)°. There is an intra-molecular O-H?N hydrogen bond.

| S-EPMC2959346 | biostudies-other

Bis[1-(2-naphthyl-imino-meth-yl)-2-naphtholato-?N,O]copper(II).

Project description:In the title complex, [Cu(C(21)H(14)NO)(2)], the Cu(II) atom, lying on an inversion center, is coordinated by two bidentate 1-(2-naphthyl-imino-meth-yl)-2-naphtholate ligands in a trans arrangement, forming a slightly distorted square-planar coordination geometry. The mean planes of two naphthyl systems of the ligand make a dihedral angle of 40.32?(11)°.

| S-EPMC2969886 | biostudies-other

{1-[(3,5-Dimethyl-4H-1,2,4-triazol-4-yl)imino]eth-yl}ferrocene.

Project description:In the title compound, [Fe(C(5)H(5))(C(11)H(13)N(4))], the triazolyl and Cp ring form a dihedral angle of 76.6?(3)°. In the crystal structure, there are both intra- and inter-molecular C-H?? inter-actions, forming a one-dimensional chain structure along [010].

| S-EPMC2959328 | biostudies-literature

Bis{?-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}copper(II)).

Project description:The title compound, [Cu2(C9H10NO2)4], is built of discrete centrosymmetric dimers. The Cu(II) atoms are each five coordinated by two deprotonated Schiff base ligands that are bonded differently to the metal atoms. Of the two phenolate O atoms, one is coordinated to one Cu(II) atom, whereas another bridges the two metal atoms. The basal plane of the square pyramid around Cu(II) atoms is formed by the imino N and phenolate O atoms of the bidentate and the monodentate/bidentate Schiff base ligands. The bridging phenolate oxygen occupies the apical position of the coordination sphere with a considerably longer Cu-O bond length. In the crystal, the dimeric mol-ecules pack relative to each other in such a way that the Cu2O2 planes of adjacent dimers are orthogonal.

| S-EPMC3790358 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data