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Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-?N,P}platinum(II) dichloro-methane hemisolvate.

ABSTRACT: In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis.

SUBMITTER: Xie Y

PROVIDER: S-EPMC2968145 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-κN,P}platinum(II) dichloro-methane hemisolvate.

Xie Yu Y Wei Ya Y Hu Jin-Gang JG Zhao Jin-Sheng JS Jiang Feng-Xing FX

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis. ...[more]

PMID: 21581754

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