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Bis(2-naphthyl-meth-yl)diphenyl-silane.

ABSTRACT: The title compound, C(34)H(28)Si, was prepared as an inter-nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra-hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42?(4)° with one another. A naphthalene system and a phenyl ring are also nearly perpendicular, making an angle of 86.18?(6)° with one another. In the crystal, the mol-ecules pack in columns parallel to the a axis, and exhibit arene C-H??(arene) inter-actions both within and between columns.

SUBMITTER: Monroe TB

PROVIDER: S-EPMC2980158 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Bis(2-naphthyl-meth-yl)diphenyl-silane.

Monroe Thomas Blake TB Thomas Andy A AA Jones Daniel S DS Ogle Craig A CA

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

The title compound, C(34)H(28)Si, was prepared as an inter-nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra-hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42 (4)° with one another. A naphthalene system and a phenyl ring are also nearly perpendicular, making an angle of 86.18 (6)° with one another. In the crystal, the mol-ecules pack in columns parallel to the a axis, and exhibit arene C-H⋯π(arene) i ...[more]

PMID: 21580023

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