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Ammonium diamminesilver(I) bis-(5-chloro-2-hy-droxy-benzene-sulfonate) trihydrate.

ABSTRACT: The reaction of silver nitrate with 5-chloro-2-hy-droxy-benzene-sulfonic acid in the presence of ammonia yielded the title salt, (NH(4))[Ag(NH(3))(2)](C(6)H(4)ClO(4)S)(2)·3H(2)O. The Ag(I) ion shows linear coordination [N-Ag-N = 175.2 (1) °]. The ammonium and diamminesilver cations, the benzene-sulfonate anion and the lattice water mol-ecules inter-act through an intricate network of N-H⋯O and O-H⋯O hydrogen bonds to form a three-dimensional network.

SUBMITTER: Deng ZP

PROVIDER: S-EPMC3274938 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Hexaaqua-magnesium bis-(3-carb-oxy-4-hy-droxy-benzene-sulfonate) dihydrate.

Project description:In the crystal structure of the title compound, [Mg(H(2)O)(6)](C(7)H(5)O(6)S)(2)·2H(2)O, the octa-hedral complex cation lies on an inversion centre and is hydrogen bonded through the coordinated water molecules to the substituted benzene-sulfonate monoanions and the water mol-ecules of solvation. These inter-actions together with a carb-oxy-lic acid O-H?O(sulfonate) association give a three-dimensional structure.

| S-EPMC3200685 | biostudies-literature

2-Amino-5-chloro-pyridinium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:The asymmetric unit of the title salt, C(5)H(6)ClN(2) (+)·C(7)H(5)O(6)S(-), contains two independent 2-amino-5-chloro-pyridinium cations and two independent 3-carb-oxy-4-hy-droxy-benzene-sulfonate anions. In both anions, the O atoms of the sulfonate group are disordered over two sets of positions, with occupancy ratios of 0.47?(5):0.53?(5) and 0.50?(8):0.50?(8). In each anion, an intra-molecular O-H?O hydrogen bond generating an S(6) motif is observed. In the crystal structure, the cations and anions are linked via N-H?O, O-H?O and C-H?O hydrogen bonds, forming a two-dimensional network parallel to (110). The structure is further stabilized by ?-? inter-actions between cations and anions [centroid-centroid distance = 3.5454?(12)?Å]. The crystal studied was a non-merohedral twin, with a ratio of the twin components of 0.715?(3):0.285?(3).

| S-EPMC3008044 | biostudies-literature

4-Methyl-anilinium 4-hy-droxy-benzene-sulfonate.

Project description:In the crystal of the title molecular salt, C7H10N(+)·C6H5O4S(-), the benzene-sulfonate units are linked through phenol-sulfonate O-H?O hydrogen bonds, forming chains along the c-axis direction. These chains are linked via N-H?O hydrogen bonds involving two of the three H atoms of the ammonium group of the 4-methyl-anilium cation, giving rise to two-dimensional networks parallel to the bc plane which are further connected through an additional N-H?O inter-action in which the third ammonium H atom is involved, generating a three-dimensional network.

| S-EPMC3648257 | biostudies-literature

Uronium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:In the title compound, CH5N2O(+)·C7H5O6S(-), the dihedral angle between the benzene ring and the mean plane of the uronium cation is 76.02?(8)°. The carboxyl group in the anion is twisted by 1.47?(9)° from the benzene ring. In the crystal, the cation is linked to the anion by weak O-H?O and N-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distance = 3.8859?(8)?Å], forming a three-dimensional network.

| S-EPMC3884371 | biostudies-literature

Glycinium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:In the anion of the title salt, C2H6NO2 (+)·C7H5O6S(-), the dihedral angle between the carb-oxy-lic acid group and the benzene ring is 5.02?(12)°. In the crystal, the anions are linked into inversion dimers through pairs of O-H?O hydrogen bonds between the carb-oxy-lic acid groups and sulfonate O atoms. A pair of C-H?O inter-actions is also observed within each dimer. The anion dimers and the cations are linked into a three-dimensional network by N-H?O, O-H?O and C-H?O hydrogen bonds.

| S-EPMC3998566 | biostudies-literature

Hexaaqua-magnesium bis-{4-[(5-bromo-2-hy-droxy-benzyl-idene)amino]-benzene-sulfonate} dihydrate.

Project description:In the title hydrated mol-ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry ) adopts a near regular MgO(6) octa-hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5?(2)° and an intra-molecular O-H?N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O-H?O and O-H?Br hydrogen bonds.

| S-EPMC3051451 | biostudies-literature

[Hydrogen bis-(1,2,4-triazole)] 1,2,4-triazolium bis-(3-carb-oxy-4-hy-droxy-benzene-sulfonate) 1,2,4-triazole disolvate.

Project description:The title compound, C(2)H(4)N(3) (+)·[H(C(2)H(3)N(3))(2)](+)·2C(7)H(5)O(6)S(-)·2C(2)H(3)N(3), consists of two types of 1,2,4-triazole monocation, one protonated at the 2-site lying across a twofold axis and the other protonated at the 4-site with the H atom disordered over a center of symmetry, a 5-sulfosalicylate anion and a neutral 1,2,4-triazole mol-ecule. The component ions are linked into a three-dimensional network by a combination of N-H?O, N-H?N, O-H?O, O-H?N, C-H?O and C-H?N hydrogen bonds. In addition, benzene-benzene ?-? inter-actions of 3.942?(2)?Å [inter-planar spacing = 3.390?(2)?Å] and C-O?? (3.331?Å) inter-actions are observed.

| S-EPMC3007327 | biostudies-literature

Bis[dieth-yl(hy-droxy)ammonium] benzene-1,4-dicarboxyl-ate.

Project description:In the centrosymmetric title compound, 2C(4)H(12)NO(+)·C(8)H(4)O(4) (2-), two N,N-dieth-yl(hy-droxy)ammonium cations are linked to a benzene-1,4-dicarboxyl-ate dianion by a combination of O-H?O and N-H?O hydrogen bonds, which can be described in graph-set terminology as R(2) (2)(7). The crystal structure is further stabilized by C-H?O hydrogen bonds, leading to the fomation of a ribbon-like network.

| S-EPMC3007286 | biostudies-other

2-Amino-3-nitro-pyridinium 4-hy-droxy-benzene-sulfonate.

Project description:In the crystal structure of the title salt, C(5)H(6)N(3)O(2) (+)·C(6)H(5)O(4)S(-), N-H⋯O and O-H⋯O hydrogen bonds link the cations and anions. The dihedral angle between the rings of the cation and anion is 79.91 (6)°.

| S-EPMC3393975 | biostudies-literature

Poly[[diaqua-bis-(2,2'-bipyridine)-bis-(?(3)-5-hy-droxy-isophthalato)(?(2)-5-hy-droxy-isophthalato)digadolinium(III)] trihydrate].

Project description:The asymmetric unit of the title coordination polymer, {[Gd(2)(C(8)H(4)O(5))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)]·3H(2)O}(n), contains two Gd(III) cations, one of which is surrounded by three 5-hy-droxy-isophthalate anions, one 2,2'-bipyridine ligand and two water mol-ecules in a distorted N(2)O(7) tricapped trigonal-prismatic coordination geometry. The other Gd cation is coordinated by four 5-hy-droxy-isophthalate anions and one 2,2'-bipyridine ligand in a distorted N(2)O(7) tricapped trigonal-prismatic coordination geometry. The 5-hy-droxy-isophthalate anions bridge the Gd cations, forming a layer structure. The layers are further connected by extensive O-H?O hydrogen bonding, assembling a three-dimensional supra-molecular network.

| S-EPMC3201312 | biostudies-literature

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