Browse
Submit Data
Databases
API
Help

Dataset Information

20 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Ammonium diamminesilver(I) bis-(5-chloro-2-hy-droxy-benzene-sulfonate) trihydrate.

ABSTRACT: The reaction of silver nitrate with 5-chloro-2-hy-droxy-benzene-sulfonic acid in the presence of ammonia yielded the title salt, (NH(4))[Ag(NH(3))(2)](C(6)H(4)ClO(4)S)(2)·3H(2)O. The Ag(I) ion shows linear coordination [N-Ag-N = 175.2 (1) °]. The ammonium and diamminesilver cations, the benzene-sulfonate anion and the lattice water mol-ecules inter-act through an intricate network of N-H⋯O and O-H⋯O hydrogen bonds to form a three-dimensional network.

SUBMITTER: Deng ZP

PROVIDER: S-EPMC3274938 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Hexaaqua-magnesium bis-(3-carb-oxy-4-hy-droxy-benzene-sulfonate) dihydrate.

Project description:In the crystal structure of the title compound, [Mg(H(2)O)(6)](C(7)H(5)O(6)S)(2)·2H(2)O, the octa-hedral complex cation lies on an inversion centre and is hydrogen bonded through the coordinated water molecules to the substituted benzene-sulfonate monoanions and the water mol-ecules of solvation. These inter-actions together with a carb-oxy-lic acid O-H⋯O(sulfonate) association give a three-dimensional structure.

| S-EPMC3200685 | biostudies-literature

2-Amino-5-chloro-pyridinium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:The asymmetric unit of the title salt, C(5)H(6)ClN(2) (+)·C(7)H(5)O(6)S(-), contains two independent 2-amino-5-chloro-pyridinium cations and two independent 3-carb-oxy-4-hy-droxy-benzene-sulfonate anions. In both anions, the O atoms of the sulfonate group are disordered over two sets of positions, with occupancy ratios of 0.47 (5):0.53 (5) and 0.50 (8):0.50 (8). In each anion, an intra-molecular O-H⋯O hydrogen bond generating an S(6) motif is observed. In the crystal structure, the cations and anions are linked via N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds, forming a two-dimensional network parallel to (110). The structure is further stabilized by π-π inter-actions between cations and anions [centroid-centroid distance = 3.5454 (12) Å]. The crystal studied was a non-merohedral twin, with a ratio of the twin components of 0.715 (3):0.285 (3).

| S-EPMC3008044 | biostudies-literature

4-Methyl-anilinium 4-hy-droxy-benzene-sulfonate.

Project description:In the crystal of the title molecular salt, C7H10N(+)·C6H5O4S(-), the benzene-sulfonate units are linked through phenol-sulfonate O-H?O hydrogen bonds, forming chains along the c-axis direction. These chains are linked via N-H?O hydrogen bonds involving two of the three H atoms of the ammonium group of the 4-methyl-anilium cation, giving rise to two-dimensional networks parallel to the bc plane which are further connected through an additional N-H?O inter-action in which the third ammonium H atom is involved, generating a three-dimensional network.

| S-EPMC3648257 | biostudies-literature

Hexaaqua-magnesium bis-{4-[(5-bromo-2-hy-droxy-benzyl-idene)amino]-benzene-sulfonate} dihydrate.

Project description:In the title hydrated mol-ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry ) adopts a near regular MgO(6) octa-hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O-H⋯O and O-H⋯Br hydrogen bonds.

| S-EPMC3051451 | biostudies-literature

Uronium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:In the title compound, CH5N2O(+)·C7H5O6S(-), the dihedral angle between the benzene ring and the mean plane of the uronium cation is 76.02?(8)°. The carboxyl group in the anion is twisted by 1.47?(9)° from the benzene ring. In the crystal, the cation is linked to the anion by weak O-H?O and N-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distance = 3.8859?(8)?Å], forming a three-dimensional network.

| S-EPMC3884371 | biostudies-literature

Glycinium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:In the anion of the title salt, C2H6NO2 (+)·C7H5O6S(-), the dihedral angle between the carb-oxy-lic acid group and the benzene ring is 5.02 (12)°. In the crystal, the anions are linked into inversion dimers through pairs of O-H⋯O hydrogen bonds between the carb-oxy-lic acid groups and sulfonate O atoms. A pair of C-H⋯O inter-actions is also observed within each dimer. The anion dimers and the cations are linked into a three-dimensional network by N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds.

| S-EPMC3998566 | biostudies-literature

Bis[dieth-yl(hy-droxy)ammonium] benzene-1,4-dicarboxyl-ate.

Project description:In the centrosymmetric title compound, 2C(4)H(12)NO(+)·C(8)H(4)O(4) (2-), two N,N-dieth-yl(hy-droxy)ammonium cations are linked to a benzene-1,4-dicarboxyl-ate dianion by a combination of O-H?O and N-H?O hydrogen bonds, which can be described in graph-set terminology as R(2) (2)(7). The crystal structure is further stabilized by C-H?O hydrogen bonds, leading to the fomation of a ribbon-like network.

| S-EPMC3007286 | biostudies-other

[Hydrogen bis-(1,2,4-triazole)] 1,2,4-triazolium bis-(3-carb-oxy-4-hy-droxy-benzene-sulfonate) 1,2,4-triazole disolvate.

Project description:The title compound, C(2)H(4)N(3) (+)·[H(C(2)H(3)N(3))(2)](+)·2C(7)H(5)O(6)S(-)·2C(2)H(3)N(3), consists of two types of 1,2,4-triazole monocation, one protonated at the 2-site lying across a twofold axis and the other protonated at the 4-site with the H atom disordered over a center of symmetry, a 5-sulfosalicylate anion and a neutral 1,2,4-triazole mol-ecule. The component ions are linked into a three-dimensional network by a combination of N-H?O, N-H?N, O-H?O, O-H?N, C-H?O and C-H?N hydrogen bonds. In addition, benzene-benzene ?-? inter-actions of 3.942?(2)?Å [inter-planar spacing = 3.390?(2)?Å] and C-O?? (3.331?Å) inter-actions are observed.

| S-EPMC3007327 | biostudies-literature

2-Hy-droxy-ethanaminium 2-methyl-5-nitro-benzene-sulfonate.

Project description:In the crystal structure of the title salt, C(2)H(8)NO(+)·C(7)H(6)NO(5)S(-), the cations and anions are linked together by N-H⋯O and O-H⋯O hydrogen bonds, forming layers parallel to (100). The plane of nitro group is skew with respect to the plane of benzene ring, making a dihedral angle of 17.5 (2)°.

| S-EPMC3435832 | biostudies-literature

2-Amino-3-nitro-pyridinium 4-hy-droxy-benzene-sulfonate.

Project description:In the crystal structure of the title salt, C(5)H(6)N(3)O(2) (+)·C(6)H(5)O(4)S(-), N-H⋯O and O-H⋯O hydrogen bonds link the cations and anions. The dihedral angle between the rings of the cation and anion is 79.91 (6)°.

| S-EPMC3393975 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data