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1-Benzoyl-2-thio-biuret.

ABSTRACT: IN THE TITLE COMPOUND [SYSTEMATIC NAME: N-(carbamoyl-carb-a-mo-thio-yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio-biuret groups are almost coplanar, making a dihedral angle of 8.48?(5)°. The mol-ecular structure is stabilized by an intra-molecular N-H?O hydrogen bond. In the crystal, N-H?O and N-H?S hydrogen bonds link the mol-ecules into a sheet parallel to the bc plane.

SUBMITTER: Kang SK

PROVIDER: S-EPMC3275072 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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1-Benzoyl-2-thio-biuret.

Kang Sung Kwon SK Cho Nam Sook NS Jeon Min Kyeong MK

Acta crystallographica. Section E, Structure reports online 20120114 Pt 2

IN THE TITLE COMPOUND [SYSTEMATIC NAME: N-(carbamoyl-carb-a-mo-thio-yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio-biuret groups are almost coplanar, making a dihedral angle of 8.48 (5)°. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen bond. In the crystal, N-H⋯O and N-H⋯S hydrogen bonds link the mol-ecules into a sheet parallel to the bc ...[more]

PMID: 22347017

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