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4,5-Diiodo-2-phenyl-1H-imidazole.

ABSTRACT: The structure of the title compound, C(9)H(6)I(2)N(2), contains two symmetry-independent mol-ecules. The inter-planar angles between the imidazole and phenyl ring planes are 16.35?(3) and 17.48?(6)°. Mol-ecules are connected via N-H?N hydrogen bonds to form zigzag chains along the b axis. The title compound is the first example of a structurally characterized 4,5-diiodo-imidazole with an organic substituent in the 2-position and without protection on the N-H group of imidazole.

SUBMITTER: Chlupaty T 

PROVIDER: S-EPMC3275288 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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4,5-Diiodo-2-phenyl-1H-imidazole.

Chlupatý Tomáš T   Pařík Patrik P   Padělková Zdeňka Z  

Acta crystallographica. Section E, Structure reports online 20120131 Pt 2

The structure of the title compound, C(9)H(6)I(2)N(2), contains two symmetry-independent mol-ecules. The inter-planar angles between the imidazole and phenyl ring planes are 16.35 (3) and 17.48 (6)°. Mol-ecules are connected via N-H⋯N hydrogen bonds to form zigzag chains along the b axis. The title compound is the first example of a structurally characterized 4,5-diiodo-imidazole with an organic substituent in the 2-position and without protection on the N-H group of imidazole. ...[more]

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