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2-Phenyl-4,5-di-2-pyridyl-1H-imidazole.

ABSTRACT: In the title compound, C(19)H(14)N(4), which was crystallized from dimethyl sulfoxide, the arene and heterocyclic rings of the lophine analogue framework differ only slightly from coplanarity (dihedral angles range from 8.8 to 20.2°), and intramolecular N-H?N and C-H?N interactions help to establish the conformation. The crystal packing features a number of weak C-H?N, N-H?N hydrogen-bond type contacts, and C-H?? interactions, leading to the formation of a herringbone structure.

SUBMITTER: Felsmann M

PROVIDER: S-EPMC2980126 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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2-Phenyl-4,5-di-2-pyridyl-1H-imidazole.

Felsmann Marika M Schindler Diana D Weber Edwin E

Acta crystallographica. Section E, Structure reports online 20091216 Pt 1

In the title compound, C(19)H(14)N(4), which was crystallized from dimethyl sulfoxide, the arene and heterocyclic rings of the lophine analogue framework differ only slightly from coplanarity (dihedral angles range from 8.8 to 20.2°), and intramolecular N-H⋯N and C-H⋯N interactions help to establish the conformation. The crystal packing features a number of weak C-H⋯N, N-H⋯N hydrogen-bond type contacts, and C-H⋯π interactions, leading to the formation of a herringbone structure. ...[more]

PMID: 21580039

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