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Efficient palladium-catalyzed cross-coupling of highly acidic substrates, nitroacetates.

ABSTRACT: Palladium-catalyzed cross-coupling conditions were developed that efficiently afford 2-aryl-2-nitroacetates from aryl bromides and the very acidic nitroacetates.

SUBMITTER: Metz AE 

PROVIDER: S-EPMC3289998 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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Efficient palladium-catalyzed cross-coupling of highly acidic substrates, nitroacetates.

Metz Alison E AE   Berritt Simon S   Dreher Spencer D SD   Kozlowski Marisa C MC  

Organic letters 20120120 3

Palladium-catalyzed cross-coupling conditions were developed that efficiently afford 2-aryl-2-nitroacetates from aryl bromides and the very acidic nitroacetates. ...[more]

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