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(E)-N-(1-Benzothio-phen-3-yl-methyl-idene)-2,6-dimethyl-aniline.

ABSTRACT: In the title compound, C(17)H(15)NS, the benzothio-phene residue and the substituted benzene ring are oriented at a dihedral angle of 61.99?(7)°. An inter-molecular C-H?? inter-action contributes to the stability of the crystal structure.

SUBMITTER: Kahveci Yagc? N

PROVIDER: S-EPMC3295420 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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(E)-N-(1-Benzothio-phen-3-yl-methyl-idene)-2,6-dimethyl-aniline.

Kahveci Yağcı Nermin N Dege Necmi N Gümüş Sümeyye S Ağar Erbil E Soylu Mustafa Serkan MS

Acta crystallographica. Section E, Structure reports online 20120204 Pt 3

In the title compound, C(17)H(15)NS, the benzothio-phene residue and the substituted benzene ring are oriented at a dihedral angle of 61.99 (7)°. An inter-molecular C-H⋯π inter-action contributes to the stability of the crystal structure. ...[more]

PMID: 22412531

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N-(2,6-Dimethyl-phen-yl)-2-methyl-acetamide.

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N-(2,6-Dimethyl-phen-yl)-2-methyl-benzamide.

Project description:In the title mol-ecule, C(16)H(17)NO, the N-H and C=O groups are in the anti-periplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methyl-phenyl ring is syn, as has also been observed in related structures. The amide group makes dihedral angles of 50.3 (3) and 64.6 (3)° with the 2-methyl-phenyl and 2,6-dimethyl-phenyl rings, respectively, while the angle between the planes of the two rings is 14.26 (7)°. The mol-ecules are packed into chains via N-H⋯O hydrogen bonds. An intramolecular C-H⋯O hydrogen bond is also observed.

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Project description:In the title compound, C(15)H(17)NO(2)S, the mol-ecule is bent at the S atom, the C-SO(2)-NH-C torsion angle being 88.0?(2)°. The dihedral angle between the two aromatic rings is 49.8?(1)°. In the crystal, mol-ecules are linked into zigzag chains parallel to the a axis via N-H?O hydrogen bonds.

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2,3-Dimethyl-N-[(E)-(1H-pyrrol-2-yl)methyl-idene]aniline.

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Project description:In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the mol-ecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O-N-C-C torsion angle = 9.0 (3)°]. The S and N atoms are syn. In the crystal, supra-molecular layers parallel to (-204) are formed by C-H⋯O and C-H⋯N inter-actions. These layers are connected into a three-dimensional architecture by π-π inter-actions occurring between centrosymmetrically related benzene rings [centroid-centroid distance = 3.6020 (11) Å].

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(E)-4-Methyl-N-[(5-nitro-thio-phen-2-yl)methyl-idene]aniline.

Project description:In the crystal structure of the title compound, C(12)H(10)N(2)O(2)S, the benzene and the 2-nitro-thio-phene rings make a dihedral angle of 7.47 (12)°. The dihedral angle between the nitro group and the attached ring is 1.9 (6)°.

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