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(E)-N-(1-Benzothio-phen-3-yl-methyl-idene)-2,6-dimethyl-aniline.

ABSTRACT: In the title compound, C(17)H(15)NS, the benzothio-phene residue and the substituted benzene ring are oriented at a dihedral angle of 61.99?(7)°. An inter-molecular C-H?? inter-action contributes to the stability of the crystal structure.

SUBMITTER: Kahveci Yagc? N

PROVIDER: S-EPMC3295420 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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(E)-N-(1-Benzothio-phen-3-yl-methyl-idene)-2,6-dimethyl-aniline.

Kahveci Yağcı Nermin N Dege Necmi N Gümüş Sümeyye S Ağar Erbil E Soylu Mustafa Serkan MS

Acta crystallographica. Section E, Structure reports online 20120204 Pt 3

In the title compound, C(17)H(15)NS, the benzothio-phene residue and the substituted benzene ring are oriented at a dihedral angle of 61.99 (7)°. An inter-molecular C-H⋯π inter-action contributes to the stability of the crystal structure. ...[more]

PMID: 22412531

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N-{(E)-[4-(Dimethyl-amino)-phen-yl]methyl-idene}-2,3-dimethyl-aniline.

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(Z)-N-{(E)-10-[(2,6-Diisopropyl-phen-yl)-imino]-9,10-dihydro-phenanthren-9-yl-idene}-2,6-dimethyl-aniline.

Project description:The title compound, C(34)H(34)N(2), adopts a Z,E configuration with respect to the N=C-C=N backbone, with an N-C-C-N torsion angle of 41.1?(4)° The dihedral angle between the benzene rings in the 9,10-dihydro-phenanthrene moiety is 18.0?(1)°.

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N-(2,6-Dimethyl-phen-yl)-2-methyl-benzamide.

Project description:In the title mol-ecule, C(16)H(17)NO, the N-H and C=O groups are in the anti-periplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methyl-phenyl ring is syn, as has also been observed in related structures. The amide group makes dihedral angles of 50.3?(3) and 64.6?(3)° with the 2-methyl-phenyl and 2,6-dimethyl-phenyl rings, respectively, while the angle between the planes of the two rings is 14.26?(7)°. The mol-ecules are packed into chains via N-H?O hydrogen bonds. An intramolecular C-H?O hydrogen bond is also observed.

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N-(2,6-Dimethyl-phen-yl)-4-methyl-benzamide.

Project description:In the mol-ecular structure of the title compound, C(16)H(17)NO, the two aromatic rings are close to orthogonal to each other [dihedral angle 78.8?(1)°], while the central -NH-C(=O)- amide core is nearly coplanar with the benzoyl ring, forming a dihedral angle of 3.5?(2)°. Inter-molecular N-H?O hydrogen bonds in the crystal structure link the mol-ecules into infinite chains running along the c axis of the crystal, and a C-H?O interaction also occurs.

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N-(2,6-Dimethyl-phen-yl)-2-methyl-acetamide.

Project description:The structure of the title compound (26DMPMA), C(11)H(15)NO, is closely related to the side-chain unsubstituted N-(2,6-dimethyl-phen-yl)acetamide and side-chain substituted N-(2,6-dimethyl-phen-yl)-2,2,2-trimethyl-acetamide and 2-chloro-N-(2,6-dimethyl-phen-yl)acetamide, with slightly different bond parameters. The mol-ecules in 26DMPMA are linked into chains through N-H⋯O hydrogen bonding.

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N-(2,6-Dimethyl-phen-yl)-4-methyl-benzene-sulfonamide.

Project description:In the title compound, C(15)H(17)NO(2)S, the mol-ecule is bent at the S atom, the C-SO(2)-NH-C torsion angle being 88.0?(2)°. The dihedral angle between the two aromatic rings is 49.8?(1)°. In the crystal, mol-ecules are linked into zigzag chains parallel to the a axis via N-H?O hydrogen bonds.

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Project description:The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61?(7)° with the benzothio-phene system ring. The benzothio-phene system and the remaining phenyl ring make an angle of 12.71?(13)°. The conformation around the imine functions is E for the C=N bond towards the benzothio-phene system and Z for the C=N bond towards the benzoyl group. The packing of the mol-ecules shows C-H?? inter-actions. A weak intramolecular C-H?N bond also occurs.

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2,3-Dimethyl-N-[(E)-(1H-pyrrol-2-yl)methyl-idene]aniline.

Project description:In the title compound, C(13)H(14)N(2), the dihedral angle between the aromatic rings is 69.73 (14)°. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate R(2) (2)(10) loops. A weak C-H⋯π inter-action also occurs.

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Project description:In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the mol-ecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O-N-C-C torsion angle = 9.0 (3)°]. The S and N atoms are syn. In the crystal, supra-molecular layers parallel to (-204) are formed by C-H⋯O and C-H⋯N inter-actions. These layers are connected into a three-dimensional architecture by π-π inter-actions occurring between centrosymmetrically related benzene rings [centroid-centroid distance = 3.6020 (11) Å].

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(E)-4-Methyl-N-[(5-nitro-thio-phen-2-yl)methyl-idene]aniline.

Project description:In the crystal structure of the title compound, C(12)H(10)N(2)O(2)S, the benzene and the 2-nitro-thio-phene rings make a dihedral angle of 7.47 (12)°. The dihedral angle between the nitro group and the attached ring is 1.9 (6)°.

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