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(Z)-2-[(E)-2-(1-Benzothio-phen-3-yl-methyl-idene)hydrazin-1-yl-idene]-1,2-diphenyl-ethanone.

ABSTRACT: The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61?(7)° with the benzothio-phene system ring. The benzothio-phene system and the remaining phenyl ring make an angle of 12.71?(13)°. The conformation around the imine functions is E for the C=N bond towards the benzothio-phene system and Z for the C=N bond towards the benzoyl group. The packing of the mol-ecules shows C-H?? inter-actions. A weak intramolecular C-H?N bond also occurs.

SUBMITTER: Pekdemir M

PROVIDER: S-EPMC3415019 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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(Z)-2-[(E)-2-(1-Benzothio-phen-3-yl-methyl-idene)hydrazin-1-yl-idene]-1,2-diphenyl-ethanone.

Pekdemir Merve M Işık Samil S Gümüş Sümeyye S Ağar Erbil E Soylu Mustafa Serkan MS

Acta crystallographica. Section E, Structure reports online 20120728 Pt 8

The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61 (7)° with the benzothio-phene system ring. The benzothio-phene system and the remaining phenyl ring make an angle of 12.71 (13)°. The conformation around the imine functions is E for the C=N bond towards the benzothio-phene system and Z for the C=N bond towards the benzoyl group. The packing of the mol-ecules shows C-H⋯π inter-actions. A weak intramolecular C-H⋯N bond also occurs. ...[more]

PMID: 22905006

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