Unknown

Dataset Information

0

6-Meth-oxy-2-phenyl-4,4a,6,7,8,8a-hexa-hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis-(4-methyl-benzene-1-sulfonate).

ABSTRACT: In the title ?-D-glucopyran-oside derivative, C(28)H(30)O(10)S(2), each heterocyclic ring adopts a chair conformation. In the tri-substituted ring, the meth-oxy and one sulfonate group occupy axial positions, whereas the second sulfonate group occupies an axial position. The phenyl group on the other ring is in an equatorial position. In the crystal, supra-molecular chains propagating along [100] are formed through C-H?O and C-H?? inter-actions.

SUBMITTER: Wardell JL 

PROVIDER: S-EPMC3295524 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

6-Meth-oxy-2-phenyl-4,4a,6,7,8,8a-hexa-hydro-2H-pyrano[3,2-d][1,3]dioxine-7,8-diyl bis-(4-methyl-benzene-1-sulfonate).

Wardell James L JL   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

In the title α-D-glucopyran-oside derivative, C(28)H(30)O(10)S(2), each heterocyclic ring adopts a chair conformation. In the tri-substituted ring, the meth-oxy and one sulfonate group occupy axial positions, whereas the second sulfonate group occupies an axial position. The phenyl group on the other ring is in an equatorial position. In the crystal, supra-molecular chains propagating along [100] are formed through C-H⋯O and C-H⋯π inter-actions. ...[more]

Similar Datasets

Unknown 6-{[(Benz-yloxy)carbon-yl]-oxy}-2-methyl-hexa-hydro-pyrano[3,2-d][1,3]dioxin-7,8-diyl bis-(chloro-acetate).
| S-EPMC2983506 | biostudies-literature
Unknown 5-Phenyl-3,4,4a,5,6,12c-hexa-hydro-2H-benzo[f]pyrano[3,2-c]quinoline.
| S-EPMC3006965 | biostudies-literature
Unknown (3R,3aR,6R,6aR)-Hexa-hydro-furo[3,2-b]furan-3,6-diyl dibenzoate.
| S-EPMC3884481 | biostudies-literature
Unknown rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa-hydro-2H-pyrano[3,2-c]quinoline.
| S-EPMC3569807 | biostudies-other
Unknown (6S,7S,8S,8aS)-6-Ethyl-7,8-dihy-droxy-1,5,6,7,8,8a-hexa-hydro-indolizin-3(2H)-one monohydrate.
| S-EPMC3011597 | biostudies-literature
Unknown Crystal structures of 4-methyl-2-oxo-2H-chromene-7,8-diyl di-acetate and 4-methyl-2-oxo-2H-chromene-7,8-diyl bis-(pent-4-ynoate).
| S-EPMC4908516 | biostudies-literature
Unknown 9-(2,3-Dichloro-phen-yl)-4a-hydr-oxy-3,3,6,6-tetra-methyl-4,4a,5,6,9,9a-hexa-hydro-3H-xanthene-1,8(2H,7H)-dione.
| S-EPMC2960184 | biostudies-literature
Unknown 5-Hy-droxy-8,8-dimethyl-10-(2-methyl-but-3-en-2-yl)-2H,6H-7,8-dihydro-pyrano[3,2-g]chromene-2,6-dione.
| S-EPMC3051790 | biostudies-literature
Unknown 10-Phenyl-6b,7,8,9,9a,10-hexa-hydro-6H-cyclo-penta-[4,5]pyrano[3,2-c]chromen-6,9-dione.
| S-EPMC3099813 | biostudies-other
Unknown 5,6-Dimethyl-1,2,9,10-tetra-hydro-pyrano[3,2-f]chromene-3,8-dione.
| S-EPMC3394011 | biostudies-literature