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Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyl-imino-methyl-?N)phenolato-?O]palladium(II).

ABSTRACT: In the title complex, [Pd(C(20)H(15)N(4)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate imine-benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-mol-ecules in both of which the Pd(II) atom lies on a centre of symmetry. The average distances between the Pd(II) atom and the coordinated O and N atoms are 1.9831?(12) and 2.012?(2)?Å, respectively.

SUBMITTER: Su JK

PROVIDER: S-EPMC3238730 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyl-imino-methyl-κN)phenolato-κO]palladium(II).

Su Jing-Kai JK Li Chen-Yu CY Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20111125 Pt 12

In the title complex, [Pd(C(20)H(15)N(4)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate imine-benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-mol-ecules in both of which the Pd(II) atom lies on a centre of symmetry. The average distances between the Pd(II) atom and the coordinated O and N atoms are 1.9831 (12) and 2.012 (2) Å, respectively. ...[more]

PMID: 22199607

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