Unknown

Dataset Information

0

(Acetato-?O)diaqua-[2-(1H-benzotriazol-1-yl)acetato-?O](1,10-phenanthroline-?N,N')manganese(II) dihydrate.

ABSTRACT: In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octa-hedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intra-molecular O-H?O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex mol-ecules and water mol-ecules are connected by O-H?O and O-H?N hydrogen bonds to generate a three-dimensional network.

SUBMITTER: Zeng L 

PROVIDER: S-EPMC3297274 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(Acetato-κO)diaqua-[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κN,N')manganese(II) dihydrate.

Zeng Ling L  

Acta crystallographica. Section E, Structure reports online 20120224 Pt 3

In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octa-hedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intra-molecular O-H⋯O hydrogen bond to the uncoordinated O atom of  ...[more]

Similar Datasets

Unknown Di-?-sulfato-?O:O'-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate.
| S-EPMC3007874 | biostudies-other
Unknown Bis(?-4-nitro-phthalato)bis-[diaqua-(1,10-phenanthroline)manganese(II)].
| S-EPMC2977488 | biostudies-literature
Unknown Di-?-sulfato-?O:O'-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline-?N,N)cobalt(II)] dihydrate.
| S-EPMC2977338 | biostudies-literature
Unknown Diaqua-bis-(1,10-phenanthroline-?N,N')manganese(II) sulfate hexa-hydrate.
| S-EPMC3009039 | biostudies-literature
Unknown Chlorido(chloro-difluoro-acetato-?O)bis(1,10-phenanthroline-?N,N')manganese(II).
| S-EPMC2961075 | biostudies-literature
Unknown Di-?-sulfato-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)iron(II)] dihydrate.
| S-EPMC3007828 | biostudies-other
Unknown Di-?-sulfato-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)nickel(II)] dihydrate.
| S-EPMC2967888 | biostudies-other
Unknown Tetra-aqua-{1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-imidazole}-sulfato-manganese(II) dihydrate.
| S-EPMC3151900 | biostudies-other
Unknown catena-Poly[[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-?-sulfato].
| S-EPMC2969714 | biostudies-literature
Unknown Aqua-chlorido{1-[1-(4-hydroxy-phen-yl)-1H-tetra-zol-5-ylsulfan-yl]acetato}(methanol)(1,10-phenanthroline)manganese(II).
| S-EPMC2959832 | biostudies-other