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Diaqua-bis-(1,10-phenanthroline-?N,N')manganese(II) sulfate hexa-hydrate.

ABSTRACT: In the title compound, [Mn(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, the complex cations assemble into positively charged sheets parallel to (010) via inter-molecular ?-? stacking inter-actions with a mean interplanar distance of 3.410?(6) along [100] and 3.465?(5)?Å along [001]. The sulfate anions and uncoordinated water mol-ecules are inter-connected between these layers by hydrogen bonds, forming negatively charged layers which are linked to the positive layers through O-H?O hydrogen bonds, forming a three-dimensional architecture. Both the positive and negative sheets are stacked along [010] in an ?ABAB? sequence, the A layers being shifted by 1/2a along [100] with respect to the B layers. One of the uncoordinated water molecules is equally disordered over two positions.

SUBMITTER: Zhang C

PROVIDER: S-EPMC3009039 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Diaqua-bis-(1,10-phenanthroline-κN,N')manganese(II) sulfate hexa-hydrate.

Zhang Chun C Zhu Hong-Lin HL

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11

In the title compound, [Mn(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, the complex cations assemble into positively charged sheets parallel to (010) via inter-molecular π-π stacking inter-actions with a mean interplanar distance of 3.410 (6) along [100] and 3.465 (5) Å along [001]. The sulfate anions and uncoordinated water mol-ecules are inter-connected between these layers by hydrogen bonds, forming negatively charged layers which are linked to the positive layers through O-H⋯O hydrogen bonds, f ...[more]

PMID: 21588867

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