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Tetra-kis(?-naphthalene-1-acetato-?O:O')bis-[(N,N-dimethyl-formamide-?O)copper(II)].

ABSTRACT: The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)O(2))(4)(C(3)H(7)NO)(2)], contains two independent centrosymmetric dinuclear copper(II) complexes. The central paddle-wheel units are formed by four bridging bidentate naphthalene-1-acetate ligands with two dimethyl-formamide ligands in the axial positions. The unique Cu(II) ions have slightly distorted square-pyramidal coordination geometries. One of the naphthalene rings is disordered over two sets of sites, with refined occpancies of 0.535?(4) and 0.465?(4).

SUBMITTER: Yin FJ

PROVIDER: S-EPMC3297287 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Tetra-kis(μ-naphthalene-1-acetato-κO:O')bis-[(N,N-dimethyl-formamide-κO)copper(II)].

Yin Fu-Jun FJ Gu Yu Y Zhao Hong H Bai Di-Si DS

Acta crystallographica. Section E, Structure reports online 20120229 Pt 3

The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)O(2))(4)(C(3)H(7)NO)(2)], contains two independent centrosymmetric dinuclear copper(II) complexes. The central paddle-wheel units are formed by four bridging bidentate naphthalene-1-acetate ligands with two dimethyl-formamide ligands in the axial positions. The unique Cu(II) ions have slightly distorted square-pyramidal coordination geometries. One of the naphthalene rings is disordered over two sets of sites, with refined occpancies of ...[more]

PMID: 22412477

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Crystal structure of di-μ-chloro-acetato-hexa-kis-(di-methyl-formamide)-tetra-kis-(μ-N,2-dioxido-benzene-1-carboximidato)tetra-manganese(III)disodium dimethyl-formamide disolvate.

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