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Tetra-kis(?-naphthalene-1-acetato-?O:O')bis-[(N,N-dimethyl-formamide-?O)copper(II)].

ABSTRACT: The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)O(2))(4)(C(3)H(7)NO)(2)], contains two independent centrosymmetric dinuclear copper(II) complexes. The central paddle-wheel units are formed by four bridging bidentate naphthalene-1-acetate ligands with two dimethyl-formamide ligands in the axial positions. The unique Cu(II) ions have slightly distorted square-pyramidal coordination geometries. One of the naphthalene rings is disordered over two sets of sites, with refined occpancies of 0.535?(4) and 0.465?(4).

SUBMITTER: Yin FJ

PROVIDER: S-EPMC3297287 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Tetra-kis(μ-naphthalene-1-acetato-κO:O')bis-[(N,N-dimethyl-formamide-κO)copper(II)].

Yin Fu-Jun FJ Gu Yu Y Zhao Hong H Bai Di-Si DS

Acta crystallographica. Section E, Structure reports online 20120229 Pt 3

The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)O(2))(4)(C(3)H(7)NO)(2)], contains two independent centrosymmetric dinuclear copper(II) complexes. The central paddle-wheel units are formed by four bridging bidentate naphthalene-1-acetate ligands with two dimethyl-formamide ligands in the axial positions. The unique Cu(II) ions have slightly distorted square-pyramidal coordination geometries. One of the naphthalene rings is disordered over two sets of sites, with refined occpancies of ...[more]

PMID: 22412477

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Tetra-kis(?-4-azido-benzoato-?O:O')bis-[(N,N-dimethyl-formamide-?O)copper(II)].

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Di-?-acetato-bis-(dimethyl-formamide)-penta-kis-(?-N,2-dioxidobenzene-1-car-boximidato)tetra-kis-(1-ethyl-imidazole)-penta-manganese(III)-manganese(II)-diethyl ether-dimethyl-foramide-methanol-water (1/1/1/1/0.12).

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| S-EPMC3212131 | biostudies-literature

(2,2'-Bi-pyridine-?(2) N,N')tetra-kis-(dimethyl sulfoxide-?O)copper(II) bis-(perchlorate).

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| S-EPMC3793687 | biostudies-literature

Tetra-kis(?(2)-phenyl-acetato-?O:O')bis-[(isoquinoline-?N)copper(II)].

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| S-EPMC2971894 | biostudies-other

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