Unknown

Dataset Information

0

Di-tert-butyl (2R,3R)-2-{[(2E)-3-(4-acet-yloxy-3-meth-oxy-phen-yl)prop-2-eno-yl]-oxy}-3-hy-droxy-butane-dioate.

ABSTRACT: In the title mol-ecule, C(24)H(32)O(10), one tert-butyl ester group is folded towards the central benzene ring while the other is directed away. The acetyl group is almost perpendicular to the benzene ring to which it is connected [C-C-O-C torsion angle = 90.4?(12)°]. The conformation about the ethene bond [1.313?(7)?Å] is E. The atoms of the benzene ring and its attached ester group and part of the hy-droxy tert-butyl ester side chain are disordered over two sets of sites in a 50:50 ratio. Linear supra-molecular chains along the a axis mediated by hy-droxy-carbonyl O-H?O hydrogen bonds feature in the crystal packing. The same H atom also partakes in an intra-molecular O-H?O inter-action.

SUBMITTER: Hixson JL 

PROVIDER: S-EPMC3297296 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Di-tert-butyl (2R,3R)-2-{[(2E)-3-(4-acet-yloxy-3-meth-oxy-phen-yl)prop-2-eno-yl]-oxy}-3-hy-droxy-butane-dioate.

Hixson Josh L JL   Taylor Dennis K DK   Ng Seik Weng SW   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20120204 Pt 3

In the title mol-ecule, C(24)H(32)O(10), one tert-butyl ester group is folded towards the central benzene ring while the other is directed away. The acetyl group is almost perpendicular to the benzene ring to which it is connected [C-C-O-C torsion angle = 90.4 (12)°]. The conformation about the ethene bond [1.313 (7) Å] is E. The atoms of the benzene ring and its attached ester group and part of the hy-droxy tert-butyl ester side chain are disordered over two sets of sites in a 50:50 ratio. Line  ...[more]

Similar Datasets

Unknown 1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acet-yloxy)phen-yl]prop-2-eno-yl}-oxy)-3-hy-droxy-butane-dioate.
| S-EPMC3275254 | biostudies-literature
Unknown (1R,2R,3R,4R,5S)-2,3-Bis[(2S')-2-acet-oxy-2-phenyl-acet-oxy]-4-azido-1-[(2,4-dinitro-phen-yl)hydrazono-meth-yl]bicyclo-[3.1.0]hexa-ne.
| S-EPMC2960152 | biostudies-literature
Unknown Crystal structure of [(2R,3R,4S)-3,4-bis(acet-yloxy)-5-iodo-3,4-di-hydro-2H-pyran-2-yl]methyl acetate.
| S-EPMC4331918 | biostudies-literature
Unknown (1R,3S,5R,6S)-6-Acet-oxy-8-methyl-3-(p-tolyl-sulfon-yloxy)-8-azoniabicyclo-[3.2.1]octane (2R,3R)-2,3-bis-(benzo-yloxy)-3-carboxy-propanoate.
| S-EPMC2977720 | biostudies-literature
Unknown Triethyl-ammonium (2R,3R)-2,3-bis-(benzo-yloxy)-3-carb-oxy-propano-ate.
| S-EPMC3295443 | biostudies-literature
Unknown Piperazine-1,4-diium 2-(carb-oxy-meth-yl)-2-hy-droxy-butane-dioate monohydrate.
| S-EPMC3007208 | biostudies-literature
Unknown 4-Hydr-oxy-3-[(2E)-3-(3,4,5-trimethoxy-phen-yl)prop-2-eno-yl]-2H-chromen-2-one.
| S-EPMC2969351 | biostudies-literature
Unknown (2E)-Methyl 2-(7-benz-yloxy-1-naphth-yl)-3-meth-oxy-acrylate.
| S-EPMC3007028 | biostudies-literature
Unknown N'-[(2E)-3-Phenyl-prop-2-eno-yl]benzo-hydrazide.
| S-EPMC2971955 | biostudies-literature
Unknown [(2R,3S,6S)-3-Acet-yloxy-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-3,6-dihydro-2H-pyran-2-yl]methyl acetate.
| S-EPMC3201326 | biostudies-literature