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(3-{[2,6-Bis(1-methyl-eth-yl)phen-yl]imino-?N}-1-phenyl-but-1-en-1-olato-?O)-di-methyl-aluminium.

ABSTRACT: The mol-ecular structure of the title compound, [Al(CH(3))(2)(C(22)H(26)NO)], displays a monomer with the Al(III) atom in a distorted tetra-hedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O-Al-N bite angle of the chelating ligand is 94.14?(9)°. The O-C-C-C-N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029?Å) and the Al atom deviates significantly from the mean plane by 0.525?(3)?Å. In the crystal, weak inter-molecular C-H?O inter-actions are observed.

SUBMITTER: Hao H 

PROVIDER: S-EPMC3343778 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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(3-{[2,6-Bis(1-methyl-eth-yl)phen-yl]imino-κN}-1-phenyl-but-1-en-1-olato-κO)-di-methyl-aluminium.

Hao Haijun H   Zhu Baichun B   Yi Jianjun J  

Acta crystallographica. Section E, Structure reports online 20120303 Pt 4

The mol-ecular structure of the title compound, [Al(CH(3))(2)(C(22)H(26)NO)], displays a monomer with the Al(III) atom in a distorted tetra-hedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O-Al-N bite angle of the chelating ligand is 94.14 (9)°. The O-C-C-C-N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029 Å) and the Al atom deviates significantly from the mean plane by 0.525 (3) Å. In the crystal, weak inter-molecul  ...[more]

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