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6,6'-Dimeth-oxy-2,2'-[(E,E')-(2,4,6-trimethyl-1,3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate.

ABSTRACT: In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33?(6) and 87.74?(6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H?N hydrogen bonds. In the crystal, an inter-molecular C-H?O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by ?-? stacking inter-actions [centroid-centroid distances = 3.739?(3)-3.776?(3)?Å] between the benzene rings of centrosymmetrically related mol-ecules.

SUBMITTER: Bahron H

PROVIDER: S-EPMC3344115 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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6,6'-Dimeth-oxy-2,2'-[(E,E')-(2,4,6-trimethyl-1,3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate.

Bahron Hadariah H Bakar Najihah Abu NA Yamin Bohari M BM Yusof M Sukeri M MS

Acta crystallographica. Section E, Structure reports online 20120324 Pt 4

In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N hydrogen bonds. In the crystal, an inter-molecular C-H⋯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by π-π stacking inter-actions [centroid-centroid distances = 3.73 ...[more]

PMID: 22606118

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