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Cyclo-octanaminium hydrogen succinate monohydrate.

ABSTRACT: In the title hydrated salt, C(8)H(18)N(+)·C(4)H(5)O(4) (-)·H(2)O, the cyclo-octyl- ring of the cation is disordered over two positions in a 0.833?(3):0.167?(3) ratio. The structure contains various O-H.·O and N-H?O inter-actions, forming a hydrogen-bonded layer of mol-ecules perpendicular to the c axis. In each layer, the ammonium cation hydrogen bonds to two hydrogen succinate anions and one water mol-ecule. Each hydrogen succinate anion hydrogen bonds to neighbouring anions, forming a chain of mol-ecules along the b axis. In addition, each hydrogen succinate anion hydrogen bonds to two water mol-ecules and the ammonium cation.

SUBMITTER: Khorasani S

PROVIDER: S-EPMC3344141 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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Cyclo-octanaminium hydrogen succinate monohydrate.

Khorasani Sanaz S Fernandes Manuel A MA

Acta crystallographica. Section E, Structure reports online 20120328 Pt 4

In the title hydrated salt, C(8)H(18)N(+)·C(4)H(5)O(4) (-)·H(2)O, the cyclo-octyl- ring of the cation is disordered over two positions in a 0.833 (3):0.167 (3) ratio. The structure contains various O-H.·O and N-H⋯O inter-actions, forming a hydrogen-bonded layer of mol-ecules perpendicular to the c axis. In each layer, the ammonium cation hydrogen bonds to two hydrogen succinate anions and one water mol-ecule. Each hydrogen succinate anion hydrogen bonds to neighbouring anions, forming a chain of ...[more]

PMID: 22606144

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