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Catena-Poly[(dichloridozinc)-?-1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole-?(2)N(3):N(3')].

ABSTRACT: The asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(4))](n), contains a Zn(II) ion situated on a twofold rotation axis and one-half of a 1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole (L) ligand with the benzene ring situated on an inversion center. The Zn(II) ion is coordinated by two chloride anions and two N atoms from two L ligands in a distorted tetra-hedral geometry. The L ligands bridge ZnCl(2) fragments into polymeric chains parallel to [20-1].

SUBMITTER: Wang C

PROVIDER: S-EPMC3344354 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole-κ(2)N(3):N(3')].

Wang Cheng C Wen Bo B Sun Zhi-Yao ZY Yan Peng-Fei PF Gao Jin-Sheng JS

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

The asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(4))](n), contains a Zn(II) ion situated on a twofold rotation axis and one-half of a 1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole (L) ligand with the benzene ring situated on an inversion center. The Zn(II) ion is coordinated by two chloride anions and two N atoms from two L ligands in a distorted tetra-hedral geometry. The L ligands bridge ZnCl(2) fragments into polymeric chains parallel to [20-1]. ...[more]

PMID: 22590120

Similar Datasets

catena-Poly[(dichloridozinc)-?-4,4'-bis-[(1H-imidazol-1-yl)meth-yl]biphenyl-?(2)N(3):N(3')].

Project description:In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetra-hedral geometry defined by two Cl anions and two N atoms from two 4,4'-bis-[(imidazol-1-yl)meth-yl]biphenyl ligands. The mid-point of the ligand is located on an inversion center, and shows a trans conformation. The ligands link the Zn(II) ions, forming a chain structure along [10-1].

| S-EPMC3344324 | biostudies-literature

catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(1H-imidazol-1-yl)benzene].

Project description:In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis-(imidazol-1-yl)benzene ligands, generating a distorted tetra-hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the Zn(II) atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and terminal imidazole ring is 27.82?(13)°.

| S-EPMC3011715 | biostudies-literature

catena-Poly[[[2-(2-pyrid-yl)-1H-benz-imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl-ato].

Project description:In the title compound, [Cd(C(8)H(4)O(4))(C(12)H(9)N(3))](n), each Cd(II) ion is six-coordinated in a distorted octa-hedral geometry by four carboxyl-ate O atoms from two benzene-1,4-dicarboxyl-ate anions (L), and two N atoms from one 2-(2-pyrid-yl)benzimidazole ligand. The neighboring Cd(II) ions are bridged by the L ligands, forming a zigzag polymeric chain structure. The chains are further extended into a three-dimensional supra-molecular structure through inter-molecular N-H⋯O hydrogen bonds.

| S-EPMC2977500 | biostudies-literature

catena-Poly[[(diiodidocadmium)-μ-{1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole-κN:N'}] N,N-dimethyl-formamide monosolvate].

Project description:In the title complex, {[CdI(2)(C(11)H(10)N(4))]·C(3)H(7)NO}(n), the Cd(II) ion is four-coordinated by two N atoms from two 1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole (bmi) ligands and by two terminal I(-) anions in a distorted tetra-hedral geometry. One of the two I(-) anions is disordered over two sets of sites, with refined occupancies of 0.66 (5) and 0.34 (5). The Cd(II) ions are bridged by bmi ligands, leading to the formation of a chain along [001]. Dimethyl-formamide solvent mol-ecules are located between these chains. Classical N-H⋯O hydrogen bonding between the bmi ligands and the solvent mol-ecules leads to a consolidation of the structure.

| S-EPMC3238781 | biostudies-literature

Monoclinic polymorph of 4-[(1H-benz-imidazol-1-yl)meth-yl]benzoic acid.

Project description:Three polymorphs of the title compound, C(15)H(12)N(2)O(2), were obtained accidentally as single crystals in the hydro-thermal reaction of the title compound with manganese bromide in the presence of N,N'-dimethyl-formamide at 373?K. Here we report the structure of the first polymorph. The benzimidazole ring is almost planar, the maximum deviation from the mean plane being 0.016?(1)?Å. The benzimidazole and benzene rings are approximately perpendicular, making a dihedral angle 85.56?(7)°, which is a reflection of the axial rotation of the flexible benzimidazolyl arm. In the crystal, adjacent mol-ecules are connected through O-H?N hydrogen bonds into a chain along [100], and neighboring chains are further linked by via weak C-H?O hydrogen-bonding inter-actions, forming a two-dimensional network.

| S-EPMC3201311 | biostudies-literature

catena-Poly[iron(II)-bis-{?-5-carb-oxy-2-[(1H-1,2,4-triazol-1-yl)meth-yl]-1H-imidazole-4-carboxyl-ato}].

Project description:In the title coordination polymer, [Fe(C(8)H(6)N(5)O(4))(2)](n) {or [FeL(2)](n),where HL = 2-[(1H-1,2,4-triazol-1-yl) meth-yl]-1H-imidazole-4,5-dicarb-oxy-lic acid)}, the Fe(II) ion, located on an inversion centre, is six-coordinated by two O atoms and four N atoms from two L(-) ligands in a distorted octa-hedral geometry [Fe-O = 2.1452?(13), Fe-N = 2.1316?(14) and 2.2484?(15)?Å]. There is an intra-molecular O-H?O hydrogen bond in each L(-) ligand. Being an effective tridentate bridging ligand, the deprotonated L(-) anions link two Fe(II) atoms, yielding a chain-like polymer propagating along [100]. In the crystal, these polymer chains are linked via N-H?N hydrogen bonds, forming a two-dimensional network.

| S-EPMC3201379 | biostudies-literature

catena-Poly[[chloridocadmium(II)]bis-{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido].

Project description:In the polymeric title complex, [CdCl(2)(C(12)H(13)N(5))](n), the Cd(II) atom is five-coordinated by two N atoms from two bridging 1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole (bmei) ligands, two bridging Cl atoms and one terminal Cl atom in a distorted trigonal-bipyramidal geometry. The Cd(II) atoms are connected alternately by the Cl atoms and bmei ligands, leading to a zigzag chain extending parallel to [011]. π-π inter-actions, with a centroid-centroid distance of 3.3016 (3) Å, help to stabilize the crystal packing.

| S-EPMC3151992 | biostudies-literature

2-[(1H-Imidazol-2-yl)disulfan-yl]-1H-imidazole.

Project description:In the title molecule, C(6)H(6)N(4)S(2), a twofold rotation axis passes through the mid-point of the S-S bond. The C-S-S-C torsion angle is 83.62?(17)°. ?-? stacking between imidazole rings of adjacent mol-ecules is observed in the crystal structure, the centroid-centroid distance being 3.447?(2)?Å. Inter-molecular N-H?S hydrogen bonding results in the formation of a linear chain in the c-axis direction.

| S-EPMC3201382 | biostudies-literature

catena-Poly[[(dichloridozinc)-?-4,4'-bis-(1H-imidazol-1-yl)biphenyl-?(2)N(3):N(3')] 0.25-hydrate].

Project description:In the title one-dimensional coordination polymer, {[ZnCl(2)(C(18)H(14)N(4))]·0.25H(2)O}(n), the Zn(II) atom is coordinated by two chloride ions and two 4,4'-bis-(1H-imidazol-1-yl)biphenyl ligands, generating a distorted tetra-hedral ZnCl(2)N(2) geometry. The dihedral angle between the benzene rings of the ligand is 51.0?(1)° and the dihedral angles between the benzene rings and their attached imidazole rings are 18.7?(2) and 45.9?(1)°. The bridging ligand leads to [10-1] polymeric chains in the crystal and the disordered water mol-ecule (occupancy 0.25) forms O-H?Cl hydrogen bonds.

| S-EPMC3343815 | biostudies-other

catena-Poly[[[dichloridozinc(II)]-?-1,4-bis-(1H-benzimidazol-2-yl-?N)butane] 1,4-bis-(1H-benzimidazol-2-yl)butane solvate].

Project description:In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl(2)(C(18)H(18)N(4))]·C(18)H(18)N(4)}(n), the tetrahedrally coordinated Zn(II) ions are linked by the N-heterocycle into a linear chain. Another N-heterocycle present is not coordinated to the metal atom but inter-acts with the chain through N-H?N and N-H?Cl hydrogen bonds. The butyl chain of the uncoordinated ligand is disordered over three positions in a 0.511?(4):0.289?(5):0.200?(5) ratio.

| S-EPMC2980004 | biostudies-literature

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