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Catena-Poly[(dichloridozinc)-?-1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole-?(2)N(3):N(3')].


ABSTRACT: The asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(4))](n), contains a Zn(II) ion situated on a twofold rotation axis and one-half of a 1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole (L) ligand with the benzene ring situated on an inversion center. The Zn(II) ion is coordinated by two chloride anions and two N atoms from two L ligands in a distorted tetra-hedral geometry. The L ligands bridge ZnCl(2) fragments into polymeric chains parallel to [20-1].

SUBMITTER: Wang C 

PROVIDER: S-EPMC3344354 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole-κ(2)N(3):N(3')].

Wang Cheng C   Wen Bo B   Sun Zhi-Yao ZY   Yan Peng-Fei PF   Gao Jin-Sheng JS  

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5


The asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(4))](n), contains a Zn(II) ion situated on a twofold rotation axis and one-half of a 1-{4-[(1H-imidazol-1-yl)meth-yl]benz-yl}-1H-imidazole (L) ligand with the benzene ring situated on an inversion center. The Zn(II) ion is coordinated by two chloride anions and two N atoms from two L ligands in a distorted tetra-hedral geometry. The L ligands bridge ZnCl(2) fragments into polymeric chains parallel to [20-1]. ...[more]

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