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ABSTRACT:
SUBMITTER: Avramovic N
PROVIDER: S-EPMC2915161 | biostudies-literature | 2007 Dec
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20071221 Pt 1
The crystal structure of the title compound, [WBr(NO)(C(6)H(16)P(2))(2)], reveals a distorted octa-hedral geometry around the W centre. The W atom lies on a special position at an inversion centre (the Br and NO ligands are equally disordered). The bis-(dimethyl-phosphino)ethane ligand is also severely disordered (site occupancy factors 0.52 and 0.48). This is the first structure of a tungsten species with nitrosyl and bromide ligands. ...[more]