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Bromido{N-methyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}-(thio-cyanato-?N)-copper(II).

ABSTRACT: In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio-cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H?Br hydrogen bonds into chains propagating along [101].

SUBMITTER: Liu LJ

PROVIDER: S-EPMC3007341 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Bromido{N-methyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}-(thio-cyanato-κN)-copper(II).

Liu Li-Jun LJ

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio-cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯Br hydrogen bonds into chains propagating along [101]. ...[more]

PMID: 21588171

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Project description:In the title compound, [CuCl(2)(C(11)H(17)N(3))], the Cu(II) ion is five-coordinated with a distorted square-pyramidal configuration. The three N atoms of the Schiff base ligand and one Cl atom are located in the basal plane, whereas the other Cl atom is apically positioned.

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{N-Methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}-bis(thio-cyanato-?N)zinc(II).

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