Unknown

Dataset Information

0

Tris(1,10-phenanthrolin-1-ium) hexa-cyanidoferrate(III) ethanol monosolvate trihydrate.

ABSTRACT: The asymmetric unit of the title complex, (C(12)H(9)N(2))(3)[Fe(CN)(6)]·C(2)H(5)OH·3H(2)O, consists of two half [Fe(CN)(6)](3-) anions located on inversion centers, three 1,10-phenanthrolin-1-ium cations, [Hphen](+), an ethanol and three water solvent mol-ecules. The average Fe-C and C-N bond lengths are 1.942?(6) and 1.154?(3)?Å, respectively, while the Fe-C-N angles deviate slightly from linearity with values ranging from 177.8?(2) to 179.7?(2)°. The Fe(III) atoms adopt a distorted octa-hedral geometry. All the species are linked through O-H?N, N-H?O and O-H?O hydrogen-bonding inter-actions, resulting in a three-dimensional supra-molecular network.

SUBMITTER: Liu XQ 

PROVIDER: S-EPMC3344416 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tris(1,10-phenanthrolin-1-ium) hexa-cyanidoferrate(III) ethanol monosolvate trihydrate.

Liu Xiao-Qing XQ   Yu Deng-Yong DY   Yuan Ai-Hua AH  

Acta crystallographica. Section E, Structure reports online 20120428 Pt 5

The asymmetric unit of the title complex, (C(12)H(9)N(2))(3)[Fe(CN)(6)]·C(2)H(5)OH·3H(2)O, consists of two half [Fe(CN)(6)](3-) anions located on inversion centers, three 1,10-phenanthrolin-1-ium cations, [Hphen](+), an ethanol and three water solvent mol-ecules. The average Fe-C and C-N bond lengths are 1.942 (6) and 1.154 (3) Å, respectively, while the Fe-C-N angles deviate slightly from linearity with values ranging from 177.8 (2) to 179.7 (2)°. The Fe(III) atoms adopt a distorted octa-hedral  ...[more]

Similar Datasets

Unknown Tris(3,4,7,8-tetra-methyl-1,10-phenanthrolin-1-ium) hexa-cyanidocobaltate(III) penta-hydrate.
| S-EPMC3588511 | biostudies-literature
Unknown 2,9-Dimethyl-1,10-phenanthrolin-1-ium tetra-chloridoferrate(III) methanol monosolvate.
| S-EPMC3393176 | biostudies-literature
Unknown 1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction.
| S-EPMC2980100 | biostudies-literature
Unknown 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin-1-ium tetra-chloridoaurate(III).
| S-EPMC2977548 | biostudies-literature
Unknown Bis(1,10-phenanthrolin-1-ium) hexa-bromidoplatinate(IV) dihydrate.
| S-EPMC2979881 | biostudies-other
Unknown Bis(1,10-phenanthrolin-1-ium) 9,10-di-oxo-9,10-dihydroanthracene-1,5-disul-fonate hexa-hydrate.
| S-EPMC3051516 | biostudies-literature
Unknown 5,6-Dioxo-1,10-phenanthrolin-1-ium chloride.
| S-EPMC2914994 | biostudies-literature
Unknown 5,6-Dioxo-1,10-phenanthrolin-1-ium nitrate.
| S-EPMC2915341 | biostudies-literature
Unknown 2,2'-(1,10-Phenanthrolin-2-ylimino)di-ethanol.
| S-EPMC2968642 | biostudies-literature
Unknown 5,6-Dihydr-oxy-1,10-phenanthrolin-1-ium chloride dihydrate.
| S-EPMC2970196 | biostudies-literature