Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

2,2'-(1,10-Phenanthrolin-2-ylimino)di-ethanol.

ABSTRACT: In the title compound, C(16)H(17)N(3)O(2), symmetry-related mol-ecules are linked into one-dimensional chains along the a axis by a combination of inter-molecular O-H?N and O-H?O hydrogen bonds and weak ?-? stacking inter-actions with a centroid-centroid distance of 3.5494?(12)?Å.

SUBMITTER: Jin X

PROVIDER: S-EPMC2968642 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

2,2'-(1,10-Phenanthrolin-2-ylimino)di-ethanol.

Jin Xia X Li Jin Min JM

Acta crystallographica. Section E, Structure reports online 20090218 Pt 3

In the title compound, C(16)H(17)N(3)O(2), symmetry-related mol-ecules are linked into one-dimensional chains along the a axis by a combination of inter-molecular O-H⋯N and O-H⋯O hydrogen bonds and weak π-π stacking inter-actions with a centroid-centroid distance of 3.5494 (12) Å. ...[more]

PMID: 21582200

Similar Datasets

Dichlorido[2,2'-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II).

Project description:In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O-H?O and O-H?Cl hydrogen bonds involving hydr-oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a ?-? stacking inter-action between adjacent 1,10-phenanthroline rings, with a distance of 3.675?(2)?Å between the centroids of the pyridine and benzene rings.

| S-EPMC2970345 | biostudies-literature

5,6-Di-oxo-1,10-phenanthrolin-1-ium trifluoro-methane-sulfonate.

Project description:In the structure of the title salt, C(12)H(7)N(2)O(2) (+)·CF(3)SO(3) (-), the cation participates in hydrogen bonding with the dione group of an adjacent cation as well as with the trifluoro-methane-sulfonate anion. In addition, there is an extensive network of C-H⋯O inter-actions between the cations and anions. There are two formula units per asymmetric unit. The crystal studied exhibits inversion twinning.

| S-EPMC2962167 | biostudies-literature

Tris(1,10-phenanthrolin-1-ium) hexa-cyanidoferrate(III) ethanol monosolvate trihydrate.

Project description:The asymmetric unit of the title complex, (C(12)H(9)N(2))(3)[Fe(CN)(6)]·C(2)H(5)OH·3H(2)O, consists of two half [Fe(CN)(6)](3-) anions located on inversion centers, three 1,10-phenanthrolin-1-ium cations, [Hphen](+), an ethanol and three water solvent mol-ecules. The average Fe-C and C-N bond lengths are 1.942?(6) and 1.154?(3)?Å, respectively, while the Fe-C-N angles deviate slightly from linearity with values ranging from 177.8?(2) to 179.7?(2)°. The Fe(III) atoms adopt a distorted octa-hedral geometry. All the species are linked through O-H?N, N-H?O and O-H?O hydrogen-bonding inter-actions, resulting in a three-dimensional supra-molecular network.

| S-EPMC3344416 | biostudies-literature

Bis(6-nitro-1,10-phenanthrolin-1-ium) 2,5-di-carb-oxy-terephthalate.

Project description:In the structure of the title 2:1 proton-transfer compound, 2C12H8N3O2 (+)·C10H4O8 (2-), the 6-nitro-1,10-phenanthroline mol-ecules act as proton sponges, accepting protons from pyromellitic acid. The -NO2 group of one of the 6-nitro-1,10-phenanthrolin-1-ium cations is disordered and was refined with a site-occupancy ratio of 0.624 (15):0.376 (15). Two -COOH(-COO(-)) groups of the 2,5-di-carb-oxy-terephthalate dianion are disordered and were refined with site-occupancy ratios of 0.769 (4):0.231 (4) and 0.766 (5):0.234 (5). The -NO2 group of the second cation is also disordered about a pseudo-twofold rotation axis and was refined with a site-occupancy ratio of 0.903 (3):0.097 (3). There is an intra-molecular O-H⋯O hydrogen bond in the anion. The phenanthroline rings of the two cations are inclined to one another by 31.3 (1)°. In the anions, considering the major components only, the carb-oxy-lic acid groups (-COOH) are inclined to the benzene ring by 17.3 (2) and 22.3 (3)°. The carboxyl-ate groups (-COO(-)) are twisted by 9.3 (2) and 13.6 (6)° with respect to the benzene ring. In the crystal, adjacent 2,5-di-carb-oxy-terephthalate anions are linked via O-H⋯O hydrogen bonds, forming chains propagating along [010]. The cations are attached to the chain of anions by N-H⋯O hydrogen bonds.

| S-EPMC3998480 | biostudies-literature

Bis(1,10-phenanthrolin-1-ium) 9,10-di-oxo-9,10-dihydroanthracene-1,5-disul-fonate hexa-hydrate.

Project description:The title hydrated molecular salt, 2C(12)H(9)N(2) (+)·C(14)H(6)O(8)S(2) (2-)·6H(2)O, consists of 1,10-phenanthrolinium (phen-H(+)) cations, anthraquinone-1,5-disulfonate (AQDS(2-)) anions, which occupy a centre of inversion, and water molecules of crystal-lization. In the crystal, a supra-molecular network structure is formed via N-H⋯O and O-H⋯O hydrogen bonds and weak C-H⋯O and π-π stacking inter-actions [centroid-centroid distances = 3.651 (6) and 3.545 (8) Å].

| S-EPMC3051516 | biostudies-literature

5,6-Dioxo-1,10-phenanthrolin-1-ium chloride.

Project description:The title compound, C(12)H(7)N(2)O(2) (+)·Cl(-), is isostructural with its bromide analogue. The compound exhibits a layered structure in which all atoms lie on a crystallographic mirror plane. N(+)-H⋯Cl(-) hydrogen bonds, C-H⋯O and C-H⋯Cl(-) contacts are formed within each layer. The perpendicular separation between the layers is 3.141 (1) Å.

| S-EPMC2914994 | biostudies-literature

5,6-Dioxo-1,10-phenanthrolin-1-ium nitrate.

Project description:In the title salt, C(12)H(7)N(2)O(2) (+)·NO(3) (-), the monoprotonated cation is connected to the nitrate anion by a hydrogen bond. Weak C-H⋯O hydrogen bonds hold the planar cations together in a layer structure.

| S-EPMC2915341 | biostudies-literature

Diaqua-(1,10-phenanthrolin-2-ol)nickel(II) dinitrate.

Project description:In the mononuclear title complex, [Ni(C(12)H(8)N(2)O)(2)(H(2)O)(2)](NO(3))(2), the Ni(II) ion is coordinated in a distorted octa-hedral geometry. The dihedral angle between the two mean planes defined by the phenanthroline ligands is 88.26?(6)°. Intra- and intermolecular O-H?O hydrogen bonds between the cation and the anions lead to the formation of a layered arrangement parallel to (010).

| S-EPMC2977106 | biostudies-literature

5,6-Dihydr-oxy-1,10-phenanthrolin-1-ium chloride dihydrate.

Project description:The title compound, C(12)H(9)N(2)O(2) (+)·Cl(-)·2H(2)O, exhibits a layered structure which is stabilized by inter-molecular O-H?O, O-H?Cl(-) and N(+)-H?Cl(-) hydrogen bonds, and ?-? inter-actions (centroid-centroid distances = 3.654 and 3.583?Å). The distances between the molecules are 3.371 and 3.294?Å.

| S-EPMC2970196 | biostudies-literature

1,10-Phenanthrolin-1-ium hydrogen d,l-tartrate dihydrate.

Project description:In the title hydrated molecular salt, C(12)H(9)N(2) (+)·C(4)H(5)O(6) (-)·2H(2)O, the cation is almost planar (r.m.s. deviation = 0.014?Å); the carbon skeleton of the anion assumes a trans conformation [C-C-C-C torsion angle = -179.86?(14)°]. The carboxyl end of one hydrogen tartrate anion forms a short hydrogen bond to the carboxyl-ate end of another anion [O?O = 2.508?(2)?Å] in a head-to-tail manner, forming a chain; the chains and water mol-ecules inter-act, generating an O-H?O hydrogen-bonded layer. The cation binds to the layer by an N-H?O hydrogen bond.

| S-EPMC3120439 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data