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(E)-4-Amino-N'-(5-chloro-2-hy-droxy-benzyl-idene)benzohydrazide.

ABSTRACT: The title compound, C(14)H(12)ClN(3)O(2), displays an E conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 41.3?(5)°. The mol-ecular structure is stabilized by an intra-molecular O-H?N hydrogen bond. In the crystal, N-H?O and weak N-H?Cl hydrogen bonds link the mol-ecules into a three-dimensional architecture. In addition, there are weak C-H?? stacking inter-actions.

SUBMITTER: Shi ZF

PROVIDER: S-EPMC3344646 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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(E)-4-Amino-N'-(5-chloro-2-hy-droxy-benzyl-idene)benzohydrazide.

Shi Zhong-Feng ZF Li Jia-Ming JM

Acta crystallographica. Section E, Structure reports online 20120428 Pt 5

The title compound, C(14)H(12)ClN(3)O(2), displays an E conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 41.3 (5)°. The mol-ecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal, N-H⋯O and weak N-H⋯Cl hydrogen bonds link the mol-ecules into a three-dimensional architecture. In addition, there are weak C-H⋯π stacking inter-actions. ...[more]

PMID: 22590408

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