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Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C-H activation.

ABSTRACT: A novel and efficient method for the arylation of 2-arylbenzothiazoles is described via C-H activation. The desired C(Ar)-C(Ar) bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted.

SUBMITTER: Ding Q 

PROVIDER: S-EPMC3363328 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C-H activation.

Ding Qiuping Q   Ji Huafang H   Wang Dan D   Lin Yuqing Y   Yu Weihua W   Peng Yiyuan Y  

Journal of organometallic chemistry 20120701 C

A novel and efficient method for the arylation of 2-arylbenzothiazoles is described via C-H activation. The desired C(Ar)-C(Ar) bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted. ...[more]

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