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Bis[2-(benzyl-imino-meth-yl)-4-chloro-phenolato-?N,O]nickel(II).

ABSTRACT: In the mononuclear centrosymmetric title compound, [Ni(C(14)H(11)ClNO)(2)], the Ni(II) atom, lying on a center of symmetry, is four-coordinated by two O atoms and two N atoms from two Schiff base ligands, forming a slightly distorted square-planar environment. The dihedral angle between the two aromatic rings of the ligand is 72.0?(2)°. No significant hydrogen bonding or ?-? stacking inter-actions are observed.

SUBMITTER: Li ZX

PROVIDER: S-EPMC2915132 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Bis[2-(benzyl-imino-meth-yl)-4-chloro-phenolato-κN,O]nickel(II).

Li Zong-Xiao ZX Zhang Xin-Li XL Pu Xiao-Hua XH

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the mononuclear centrosymmetric title compound, [Ni(C(14)H(11)ClNO)(2)], the Ni(II) atom, lying on a center of symmetry, is four-coordinated by two O atoms and two N atoms from two Schiff base ligands, forming a slightly distorted square-planar environment. The dihedral angle between the two aromatic rings of the ligand is 72.0 (2)°. No significant hydrogen bonding or π-π stacking inter-actions are observed. ...[more]

PMID: 21200550

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