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Bis(2-aminomethyl-1H-benzimidazole-?(2)N(2),N(3))bis-(nitrato-?O)copper(II).

ABSTRACT: In the title compound, [Cu(NO(3))(2)(C(8)H(9)N(3))(2)], the Cu(II) atom, lying on an inversion center, has a distorted octa-hedral coordination environment defined by four N atoms from two chelating 2-amino-methyl-1H-benzimidazole ligands and two O atoms from two monodentate nitrate anions. In the crystal, N-H?O hydrogen bonds link the complex mol-ecules into a three-dimensional network. An intra-molecular N-H?O hydrogen bond is also observed.

SUBMITTER: Zhao J

PROVIDER: S-EPMC3379102 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Bis(2-aminomethyl-1H-benzimidazole-κ(2)N(2),N(3))bis-(nitrato-κO)copper(II).

Zhao Jing J Zhang Heng H Zhai Xueliang X Zhu Guoyi G

Acta crystallographica. Section E, Structure reports online 20120516 Pt 6

In the title compound, [Cu(NO(3))(2)(C(8)H(9)N(3))(2)], the Cu(II) atom, lying on an inversion center, has a distorted octa-hedral coordination environment defined by four N atoms from two chelating 2-amino-methyl-1H-benzimidazole ligands and two O atoms from two monodentate nitrate anions. In the crystal, N-H⋯O hydrogen bonds link the complex mol-ecules into a three-dimensional network. An intra-molecular N-H⋯O hydrogen bond is also observed. ...[more]

PMID: 22719323

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