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Dibromidobis[1-(2-bromo-benz-yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II).

ABSTRACT: In the title complex, [CuBr(2)(C(14)H(11)BrN(4)O)(2)], the Cu(II) ion is located on an inversion centre and is coordinated by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment. The two carbonyl groups are trans positioned with C=O bond lengths of 1.256?(5)?Å, in agreement with a classical carbonyl bond. The Cu-O bond length is 2.011?(3)?Å. The two bromo-benzyl rings are approximately parallel to one another, forming a dihedral angle of 70.1?(4)° with the coordination plane.

SUBMITTER: Lu CX

PROVIDER: S-EPMC3379115 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Dibromidobis[1-(2-bromo-benz-yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II).

Lu Chun-Xin CX

Acta crystallographica. Section E, Structure reports online 20120519 Pt 6

In the title complex, [CuBr(2)(C(14)H(11)BrN(4)O)(2)], the Cu(II) ion is located on an inversion centre and is coordinated by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment. The two carbonyl groups are trans positioned with C=O bond lengths of 1.256 (5) Å, in agreement with a classical carbonyl bond. The Cu-O bond length is 2.011 (3) Å. The two bromo-benzyl rings are approximately parallel to one another, forming a dihedral angle of 70. ...[more]

PMID: 22719336

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