Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tris(2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolato-?(2)N,O(1))cobalt(III).

ABSTRACT: In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa-hedral geometry by three N,O-chelating 2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolate groups. One of the three meth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.768?(5):0.232?(5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa-hedra along the c axis. There are no classical hydrogen bonds in the structure, but C-H?? inter-actions occur.

SUBMITTER: Ourari A

PROVIDER: S-EPMC3379129 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Tris(2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolato-κ(2)N,O(1))cobalt(III).

Ourari Ali A Ouennoughi Yasmina Y Bouacida Sofiane S

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa-hedral geometry by three N,O-chelating 2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolate groups. One of the three meth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa-hedra along the c axis. There are no classical hydrogen bonds in the ...[more]

PMID: 22719350

Similar Datasets

Tris[2-eth-oxy-6-(methyl-imino-meth-yl)phenolato-?N,O]cobalt(III) monohydrate.

Project description:In the title compound, [Co(C(10)H(12)NO(2))(3)]·H(2)O, the Co(III) ion is coordinated by three O atoms and three N atoms from three bidentate 2-eth-oxy-6-(methyl-imino-meth-yl)phenolate ligands in a slightly distorted octa-hedral environment. The water mol-ecule connects two ligands by O-H?O hydrogen bonds. One terminal methyl group is disordered over two positions, with site-occupancy factors of 0.412?(15) and 0.588?(15).

| S-EPMC3009188 | biostudies-other

Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]cobalt(III).

Project description:The title compound, [Co(C(10)H(12)NO)(3)], was synthesized from cobalt(III) fluoride and 2-(propyl-imino-meth-yl)phenol in refluxing methanol. The Co(III) ion is hexa-coordinated by three N and three O atoms from three bidentate Schiff base ligands in an octa-hedral geometry.

| S-EPMC2961544 | biostudies-literature

Tris{2-[(furan-2-meth-yl)imino-meth-yl]-4-methyl-phenolato}cobalt(III).

Project description:In title compound, [Co(C(13)H(12)NO(2))(3)], the Co(III) ion is six-coordinated by three bidentate Schiff base ligands in a distorted octa-hedral environment. Adjacent complex mol-ecules are linked through C-H⋯O hydrogen bonds.

| S-EPMC3247556 | biostudies-literature

{4-Chloro-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}{4-chloro-2-[(2-oxido-eth-yl)imino-meth-yl]phenolato}cobalt(III).

Project description:In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy-droxy and one oxide O atom from two Schiff base ligands, forming an octa-hedral geometry. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds. The 2-oxidoethyl group is disordered over two positions in a 0.638 (3):0.362 (3) ratio.

| S-EPMC3008055 | biostudies-literature

Tris[2,4-dichloro-6-(ethyl-imino-meth-yl)phenolato-?(2)N,O]cobalt(III).

Project description:The asymmetric unit of the title compound, [Co(C(9)H(8)Cl(2)NO)(3)], contains three independent mol-ecules. In each mol-ecule, the Co(III) ion is coordinated by an O atom and an N atom from three bidentate 2,4-dichloro-6-(ethyl-imino-meth-yl)phenolate ligands in a slightly distorted octa-hedral environment. In the crystal, a weak C-H?Cl hydrogen bond is observed.

| S-EPMC3414116 | biostudies-literature

Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-?(2) N,O]cobalt(III).

Project description:In the title compound, [Co(C8H7BrNO)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl-imino-meth-yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6?(2), 57.1?(2) and 62.9?(2)°. In the crystal, mol-ecules are linked by pairs of weak C-H?Br hydrogen bonds, forming inversion dimers.

| S-EPMC3884257 | biostudies-literature

Crystal structure of di-chlorido-bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}{2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}cadmium(II)cobalt(III) monohydrate.

Project description:The title compound, [CoCd(C9H10NO2)3Cl2]·H2O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171-184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume. The title compound is formed of discrete neutral dinuclear mol-ecules with no crystallographically imposed symmetry and water mol-ecules of crystallization. The overall geometry about the cobalt(III) ion is octa-hedral with an N3O3 environment; each ligand acts as a meridional ONO donor. The CdII coordination sphere approximates an irregular square pyramid with a chlorine atom at the apex. There is significant shortening of a Cd-O bond length to the oxygen atom of the methoxo group on one of the ligands [2.459 (3) Å] compared to the corresponding distance in the published structure [2.724 (7) Å], while other Cd-Cl/N/O bonds remain roughly the same. In the crystal lattice, the heterometallic mol-ecules, which are related by the crystallographic n-glide plane and inter-linked by weak hydrogen bonds to solvent water mol-ecules, form columns along [101]. Adjacent columns lie anti-parallel to each other.

| S-EPMC6218914 | biostudies-literature

Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)-meth-yl]-imino-meth-yl}phenolato)-copper(II) dihydrate.

Project description:In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa-hedral geometry arising from two N,O,O'-tridentate 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]-imino-meth-yl}phenolate ligands. The Jahn-Teller distortion of the copper centre is unusally small. In the crystal structure, O-H?O hydrogen bonds, some of which are bifurcated, link the component species.

| S-EPMC2968260 | biostudies-literature

Tris[2-(benzyl-imino-meth-yl)phenolato-κN,O]iron(III).

Project description:In the title compound, [Fe(C(14)H(12)NO)(3)], the Fe(III) atom has a slightly distorted octa-hedral geometry and is coordinated by three Schiff base ligands, viz. 2-(benzyl-imino-methyl)-phenolate. The crystal structure is stabilized by intra-molecular C-H⋯O and C-H⋯N hydrogen bonds.

| S-EPMC2960378 | biostudies-literature

Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III).

Project description:The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms.

| S-EPMC2961833 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data